40934-76-7Relevant academic research and scientific papers
Bimetallic Nanoshells as Platforms for Metallo- and Biometallo-Catalytic Applications
Kisukuri, Camila M.,Palmeira, Dayvson J.,Rodrigues, Thenner S.,Camargo, Pedro H.C.,Andrade, Leandro H.
, p. 171 - 179 (2016)
The use of gold, silver, platinum and palladium for preparation of bimetallic nanoshells (AgAu, AgPt, and AgPdNSs, respectively) and their use for metallo- and bio-metallo catalytic applications have been described. Bimetallic nanoshells (metallo-catalysts) were employed for silane oxidation to silanols and hydrogen (H2) production. Fast and efficient oxidation of several silanes was observed after only 1 h at room temperature, by employing AgPd NSs as catalyst, acetone as solvent, and water as oxidant. Interestingly, bio-metallo-catalysts (NSs-CALB) prepared from lipase attachment to the bimetallic nanoshells, displayed promising bi-catalytic activities (enzymatic: transesterification; metallic: silane oxidation).
Intermolecular Dehydrogenative C?H/Si?H Cross-Coupling for the Synthesis of Arylbenzyl Bis(silanes)
He, Chuan,You, Lijun,Yuan, Wei
supporting information, p. 3079 - 3082 (2021/07/22)
An iridium-catalyzed intermolecular dehydrogenative C?H/Si?H cross-coupling reaction for the synthesis of arylbenzyl bis(silanes) is developed. This hydrosilyl group steered intermolecular C?H silylation process features high chemo- and regioselectivity,
Nucleophile-assisted racemisation of halosilanes; an alternative pathway involving halide exchange
Bassindale, Alan R.,Lau, Juliana C.-Y.,Taylor, Peter G.
, p. 213 - 224 (2007/10/02)
An NMR method using diastereotopic halosilanes, PhCH(Me)SiMe2X (X = Cl or Br) has been developed for studying nucleophile-assisted racemisations of halosilanes.A mechanism for racemisation involving halide exchange is proposed to account for the observati
