4099-01-8Relevant academic research and scientific papers
Substituted lithiumtrimethylsiloxysilanides LiSiRR′(OSiMe3) - Investigations of their synthesis, stability and reactivity
Harloff, Joerg,Popowski, Eckhard,Reinke, Helmut
, p. 1421 - 1441 (2007/10/03)
The reactions of the trimethylsiloxychlorosilanes (Me3SiO)RR′SiCl (1a-h: R′ = Ph, 1a: R = H, 1b: R = Me, 1c: R = Et, 1d: R = iPr, 1e: R = tBu, 1f: R = Ph, 1g: R = 2,4,6-Me3C6H2 (Mes), 1h: R
Silenes as novel synthetic reagents: Identification of a practical method for silene generation and trapping
Berry, Malcolm B.,Griffiths, Russell J.,Sanganee, Mahesh J.,Steel, Patrick G.,Whelligan, Daniel K.
, p. 2381 - 2392 (2007/10/03)
The elucidation of a robust and reliable sequence for the generation of highly reactive transient silenes from simple aldehydes is described. The key step involves a silyl-modified Peterson olefination which critically depends on the presence of a sub-sto
