41318-92-7Relevant academic research and scientific papers
Synthesis of phenyl or 4-nitrophenyl methyl β-ketophosphonate esters
Reddy, Putta M.,Viragh, Carol,Kovach, Ildiko M.
, p. 1597 - 1600 (2007/10/03)
Seven new aryl methyl β-ketophosphonate esters were synthesized. The hydrolytic rates of the compounds under physiological conditions were studied. Most of the compounds are effective inhibitors of acetylcholinesterase. The enzyme recovers on the 10-50 h
New organohypervalent iodine reagents for α-methylphosphonylations and α-diphenyl- and α-dimethylphosphinylations
Moriarty, Robert M.,Condeiu, Cristian,Tao, Anping,Prakash, Om
, p. 2401 - 2404 (2007/10/03)
[Hydroxy(((phenoxy)(methyl)phosphoryl)oxy)iodo]benzene (1), [hydroxy(((diphenyl)phosphoryl)oxy)iodo]benzene (2) and [hydroxy(((dimethyl)phosphoryl)oxy)iodo]benzene (3), obtained from the reaction of iodosobenzene with phenyl methylphosphonic acid, diphenyl- and dimethylphosphinic acid, respectively, effect the introduction of the corresponding phosphonate or phosphinate groups α- to ketone and eater carbonyl groups. Phenylacetylene is transformed by reagents 1-3 into the corresponding α-functionalized acetophenone derivatives.
