41481-63-4Relevant articles and documents
Preparation method of diallyl bisphenol S ether
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Paragraph 0033-0044, (2020/12/30)
The invention discloses a preparation method of diallyl bisphenol S ether. The preparation method comprises the following steps: adding solid alkali, bisphenol S and chloropropene into an anhydrous aprotic strong polar solvent, and reacting at 55-100 DEG C for 7-12 hours in the presence of a catalyst; carrying out solid-liquid separation, and separating diallyl bisphenol S ether and inorganic saltfrom the obtained filter cake; directly and circularly applying the filtrate containing the solvent and the catalyst to the next preparation of the diallyl bisphenol S ether, wherein the catalyst isa nonionic surfactant, and the dosage of the catalyst is at least 5% of the weight of bisphenol S. The method belongs to an anhydrous reaction, the one-time conversion rate of the raw materials is increased, and the used solvent and catalyst can be directly reused without being recycled and purified so that the problem of industrial wastewater is fundamentally solved, and high quality and high yield of target products and byproducts are realized.
Process for synthesizing diallyl phenol ether compound through azeotropic dehydration
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Paragraph 0023-0024, (2021/01/04)
The invention discloses a process for synthesizing a diallyl phenol ether compound by azeotropic dehydration, which comprises the following steps: (1) dissolving a bisphenol compound in an organic solvent, and adding an inorganic base or an aqueous solution of the inorganic base to react to generate phenolate; and (2) vacuumizing the mixture obtained by the reaction in the step (1) or adding a water-carrying agent for dehydration, adding an allyl compound after dehydration is finished, and reacting to obtain the diallyl phenol ether compound. The invention provides a method for preparing a bisphenol compound into an intermediate product phenate and then reacting the intermediate product phenate with a propenyl compound to generate a diallyl phenol ether compound product, which comprises the following steps: adding a water-carrying agent or vacuumizing to remove water in a reaction system; according to the method, the problem of raw material waste caused by hydrolysis of propylene compounds can be effectively avoided, the reaction yield and purity are improved, aftertreatment is simple, and economic benefits are improved.
PROCESS FOR THE PRODUCTION OF DIPHENYL SULFONE COMPOUNDS
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Page/Page column 6-7, (2014/11/11)
A method for controlled production of mono and diether derivatives of 4,4'-dihydroxydiphenyl sulfone (SDP) namely 4-substituted-4'-hydroxydiphenyl sulfones and 4,4'-disubstituted diphenyl sulfones in high yields by reacting alkyl halide and the like, with 4,4'- dihydroxydiphenyl sulfone. 4-substituted-4'-hydroxydiphenyl sulfone is prepared by reacting equimolar ratio of 4,4'-dihydroxydiphenyl sulfone, alkyl halide and aqueous alkali solution with >80% yield. 4,4'-disubstituted diphenyl sulfone is prepared by reacting one mole of 4,4'- dihydroxydiphenyl sulfone, two moles of alkyl halide and like and two moles of aqueous alkali solution with >80% yield. The method of invention is useful in production of diphenyl sulfone compounds such as 4-allyloxy-4'-hydroxydiphenyl sulfone, 4,4'-diallyloxydiphenyl sulfone, 4-isopropxy-4'-hydroxydiphenyl sulfone, 4,4'-diisopropoxydiphenyl sulfone, 4- benzyloxy-4'-hydroxydiphenyl sulfone, 4,4'-dibenzyloxydiphenyl sulfone etc. This is a commercially feasible green manufacturing process.