41563-50-2Relevant academic research and scientific papers
A General Preparative Method for Carbonyl-Protected γ-Lithioketones via Reductive Lithiation. Synthetic Uses of the Bishomoenolate Equivalents
Cohen, Theodore,Zhang, Birong,Cherkauskas, John P.
, p. 11569 - 11584 (2007/10/02)
The mixed cuprates, generated by reductive lithiation of bis(phenylthio)acetals using lithium 4,4'-di-tert-butylbiphenylide (LDBB), followed by addition of cuprous bromide-dimethyl sulfide complex, undergo conjugate addition to enones in the presence of t
ELIMINATION OF THIOPHENOL FROM PHENYL ORTHOTHIOESTERS IN THE MASS SPECTROMETER AND NOVEL REARRANGEMENT OF KETENE THIOACETALS UPON ELECTRON IMPACT
El-Khawaga, Ahmed M.,El-Zohry, Maher F.
, p. 179 - 183 (2007/10/02)
The mass spectra of four selected phenyl orthothioesters (1-4) have been measured.The obtained spectra revealed the conversion of the compounds (1-4) into ketene thioacetals (5-8) via the elimination of thiophenol in the mass spectrometer.The thermal natu
