83078-46-0

Upstream product

• 75-15-0 carbon disulfide 
• 13464-19-2 phenyl chlorothioformate 
• 930-69-8 sodium thiophenolate 
• 35329-04-5 2-methylpropanedithioic acid 
• 100-63-0 phenylhydrazine 
• 81837-94-7 4,4-dimethyl-2-phenyl-1,3-thiazole-5(4H)-thione 
• 591-51-5 phenyllithium 
• 58443-71-3 S-phenyl 2-methylpropanethioate 
• 108-98-5 thiophenol 
• 64035-95-6 bis sulfide 

Downstream Products

• 629-45-8 dibutyl disulfide 
• 108-98-5 thiophenol 
• 107195-31-3 2-Methyl-dithiopropionsaeure-butylester 
• 882-33-7 diphenyldisulfane 
• 519-73-3 triphenylmethane 
• 58443-71-3 S-phenyl 2-methylpropanethioate 
• 41563-50-2 1,1-bis(phenylthio)-2-methylpropene 
• 29627-34-7 4-(phenyldisulfanyl)toluene 
• 104411-50-9 S-(p-tolyl) 2-methylpropanethioate 
• 104411-48-5 dimethylketene phenyl p-tolyl mercaptal 

Relevant academic research and scientific papers

Compound embodiments that release H2S by reaction with a reactive compound and methods of making and using the same

Disclosed herein are embodiments of a donor compound that releases H2S by reacting with a reactive compound. The donor compound embodiments described herein can be used to deliver H2S to a subject or a sample and further can be used to administer therapeutic agents. The donor compound embodiments also can facilitate bioconjugation. Methods of making and using the donor compound embodiments also are disclosed.

CATALYZED AMINATION OF DITHIOACID SODIUM SALTS: A ONE POT SYNTHESIS OF α-PHOSPHONOTHIOAMIDES

Ab efficient synthesis of α-phosphonothioamides is described, involving thioacylation of primary or secondary amines with α-phosphonodithioacid salts (prepared in situ), in the presence of boron trichloride.This method can also be used for the preparation of non-phosphorylated thioamides.In the same conditions and with thiophenol, a dithioacid sodium salt is converted into the S-arylthioester, while an α-phosphorylated dithioacid sodium salt is reduced into the bis (phosphonomethyl) disulfide. Key words: Thioacylation; α-phosphonothioamides; thioamides; boron trichloride.

B-THIOACYLTHIO-9-BBN AS A THIOACYLATING REAGENT

Convenient synthesis of S-aryldithioesters and thioamides are described: thus, thiols and amines are readily thioacylated with the S-borondithioester formed in situ, by the mild reaction of a dithioacid with 9-BBN.

A New Rapid Synthesis of Phenyl Dithiocarboxylates

The otherwise difficultly accessible phenyl dithiocarboxylates are prepared in good yields by the reaction of S-phenyl carbonochloridothioate with halomagnesium or sodium dithiocarboxylates.

Reactions of 1,3-Thiazole-5(4H)-thiones with Grignard- and Organolithium Compounds: Carbophilic and Thiophilic Additions

Organolithium compounds and 1,3-thiazole-5(4H)-thiones 9 reacted via thiophilic addition on the exocyclic S-atom.The intermediate anion E has been trapped by protonation to give 12 and by alkylation to yield 16, respectively (Schemes 5 and 6).In competiti

Preparation and Some Reactions of Bis(thioacyl) Sulfides

Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.