4163-39-7

Basic information

• Product Name: 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl fluoride
• Synonyms: 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl fluoride
• CAS NO: 4163-39-7
• Molecular Weight: 598.581
• Mol File: 4163-39-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl fluoride(4163-39-7)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl fluoride(4163-39-7)

Safety Data

• Hazardous Substances Data: 4163-39-7(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 2106-10-7 1-deoxy-1-fluoro-α-D-glucose 
• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 2713-54-4 α-D-mannopyranosyl fluoride 
• 125367-09-1 n-pent-4-enyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside 
• 123487-55-8 3,4,6-tri-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate) 
• 66888-27-5 penta-O-acetyl-D-mannose 
• 1392228-57-7 tolyl 2,3,4,6-tetra-O-benzoyl-1-thio-α-D-mannopyranoside (R)-S-oxide 
• 950602-83-2 4-methylphenyl 2,3,4,6-tetra-O-benzoyl-1-thio-α-D-mannopyranoside 
• 65236-82-0 1,2-O-(α-methoxybenzylidene)-3,4,6-tri-O-benzoyl-β-D-mannopyranose 
• 3947-62-4 2,3,4,6-tetra-O-acetyl-D-mannopyranose 
• 2823-44-1 2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl fluoride 
• 65236-83-1 phenyl 2,3,4,6-tetra-O-benzoyl-1-thio-α-D-mannopyranoside 
• 4410-31-5 (RS)-mandelamide 

Downstream Products

• 128503-39-9 methyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 128503-40-2 methyl-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 125135-28-6 methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 118579-76-3 methyl 4-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

IPy2BF4/HF-pyridine: A new combination of reagents for the transformation of partially unprotected thioglycosides and n-pentenyl glycosides to glycosyl fluorides

(Chemical Equation Presented) The combination of bis(pyridinium)iodonium (I) tetrafluoroborate (IPy2BF4), and hydrogen fluoride pyridine (HF-py) forms an iodine monofluoride (IF) synthetic equivalent that can be used in the preparati

Glycosyl fluorides from n-pentenyl-related glycosyl donors-application to glycosylation strategies

n-Pentenyl glycosides (NPGs) and n-pentenyl orthoesters (NPOEs) have been transformed into glycosyl fluorides by a variety of methods. In the case of NPGs, Barluenga's reagent, bis(pyridinium)iodonium(I)tetrafluoroborate (IPy 2BF4),

Unexpected stereocontrolled access to 1α,1′β-disaccharides from methyl 1,2-ortho esters

Mannopyranose-derived methyl 1,2-orthoacetates (R = Me) and 1,2-orthobenzoates (R = Ph) undergo stereoselective formation of 1α,1′β-disaccharides, upon treatment with BF 3?Et2O in CH2Cl2, rather than the expected acid-catalyzed reaction leading to methyl glycosides by way of a rearrangement-glycosylation process of the liberated methanol.