125367-09-1Relevant academic research and scientific papers
Cross metathesis assisted solid-phase synthesis of glycopeptoids
Khan, Sharaf Nawaz,Kim, Arim,Grubbs, Robert H.,Kwon, Yong-Uk
, p. 2952 - 2955 (2012/07/30)
A solid-phase synthesis of glycopeptoids was explored through olefin cross metathesis (CM). Peptoids and sugar derivatives with appropriate olefin moieties were coupled in the presence of an olefin metathesis catalyst to afford glycopeptoids in good yield
Propargyl 1,2-orthoesters as glycosyl donors: stereoselective synthesis of 1,2-trans glycosides and disaccharides
Sureshkumar, Gopalsamy,Hotha, Srinivas
, p. 6564 - 6568 (2008/02/12)
Propargyl 1,2-orthoesters are identified as glycosyl donors. Various glycosides and disaccharides were synthesized in a stereoselective manner using AuBr3 as the promoter. AuBr3 may activate the alkyne resulting in the formation of a
n-Pentenyl glycosides in the efficient assembly of the blood group substance B tetrasaccharide
Udodong,Rao,Fraser-Reid
, p. 4713 - 4724 (2007/10/02)
The fact that n-pentenyl glycosides (nPGs) are stable to a wide variety of reaction conditions but yet can be chemospecifically activated is advantageous for the efficient, convergent assembly of oligosaccharides. The nPGs are prepared directly from the a
