41774-06-5

Basic information

• Product Name: Benzene, [(1-methyl-1-nitroethyl)sulfonyl]-
• CAS NO: 41774-06-5
• Molecular Formula: C9H11NO4S
• Molecular Weight: 229.257
• Mol File: 41774-06-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methyl-1-nitroethyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methyl-1-nitroethyl)sulfonyl]-(41774-06-5)
• EPA Substance Registry System: Benzene, [(1-methyl-1-nitroethyl)sulfonyl]-(41774-06-5)

Safety Data

• Hazardous Substances Data: 41774-06-5(Hazardous Substances Data)

Upstream product

• 873-55-2 sodium benzenesulfonate 
• 75376-78-2 1-methyl-1-nitroethyl p-chlorophenyl sulphoxide 
• 75376-76-0 1-methyl-1-nitroethyl 2,4-dinitrophenyl sulphide 
• 66463-89-6 1-methyl-1-nitroethyl p-nitrophenyl sulphide 
• 595-49-3 2,2-dinitropropane 
• 38590-81-7 2-iodo-2-nitropropane 
• 5447-97-2 2-bromo-2-nitropropane 
• 594-71-8 2-chloro-2-nitro-propane 
• 79-46-9 2-nitropropane 

Downstream Products

• 3964-18-9 2,3-dimethyl-2,3-dinitrobutane 
• 52755-34-7 1-methyl-1-nitroethyl p-chlorophenyl sulphide 
• 77-76-9 2,2-dimethoxy-propane 
• 79-46-9 2-nitropropane 

Relevant articles and documents

Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.

Oxidative Substitution of Nitroparaffin Salts

α,α-Dinitro compounds, α-nitro sulfones, and α-nitro nitriles are obtained in excellent yields when nitroparaffin salts are coupled to nitrite, benzenesulfinate, and cyanide ions by the agency of potassium ferricyanide.