4181-21-9Relevant articles and documents
A highly luminescent chiral tetrahedral Eu4L4(L′)4 cage: Chirality induction, chirality memory, and circularly polarized luminescence
Zhou, Yanyan,Li, Hongfeng,Zhu, Tianyu,Gao, Ting,Yan, Pengfei
, p. 19634 - 19643 (2019)
Chiral lanthanide cages with circularly polarized luminescence (CPL) properties have found potential application in enantioselective guest recognition and sensing. However, it still remains a big challenge to develop a simple and robust method for the dia
Multi-Component Metal-Organic Frameworks Significantly Boost Visible-Light-Driven Hydrogen Production Coupled with Selective Organic Oxidation
Duan, Chunying,He, Cheng,Jing, Xu,Li, Hanning,Yang, Yang
supporting information, p. 1237 - 1244 (2021/04/09)
Visible-light-driven hydrogen production coupled with selective organic oxidation has attracted increasing attention, as it not only provides clean and renewable energy, but also utilizes the other half reaction to achieve some value-added organic chemicals. Metal-organic frameworks based on metal clusters and organic ligands self-assembly give a perspective on the formation of multifunctional heterogeneous photocatalyst to significantly boost visible-light photocatalytic activities under mild conditions. By incorporating two types of photoactive units, tricarboxytriphenylamine (H3TCA) and tris(4-(pyridinyl)phenyl)amine (NPy3), into a single metal-organic frameworks, a multi-component MOF Co-MIX was obtained. With the redox active metal centers enabling the photoexcitation reduction of protons into hydrogen and the photogenerated holes promoting considerable oxidation of substrates, the resulting Co-MIX exhibits high catalytic activity for the photocatalytic hydrogen production coupled with selective oxidation of benzylamine or 1,2,3,4-tetrahydroisoquinoline. Importantly, the photocatalytic experiments of single-component Co-TCA and Co-NPy3 verified the positive synergistic effects on stability and photocatalytic ability of the two ligands (H3TCA and NPy3) in one single MOF, revealing that the multi-component strategy is very important for the efficient charge separation and excellent photocatalytic activity of the catalyst.
Cadmium-based metal-organic framework material as well as preparation method and application thereof
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Paragraph 0039; 0040, (2019/02/25)
The invention discloses a cadmium-based metal-organic framework material as well as a preparation method and application thereof. Metal ions Cd are used as nodes, 4,4',4''-tricarboxytriphenylamineis used as an organic linking main ligand, 4,4'-azopyri