41827-15-0

Usage

Uses

Used in Chemical Reactions and Processes:
1,2,4-triethoxybenzene is used as a solvent for its effectiveness in dissolving a variety of organic compounds, facilitating numerous chemical reactions and processes.
Used in Dye Production:
1,2,4-triethoxybenzene is used as an intermediate in the production of dyes, contributing to the synthesis of colorants for various applications.
Used in Pharmaceutical Industry:
1,2,4-triethoxybenzene is utilized as a solvent or intermediate in the manufacturing of pharmaceuticals, playing a role in the development of medicinal compounds.
Used in Fragrance Industry:
1,2,4-triethoxybenzene is employed in the production of fragrances, where its solvent properties aid in the creation of scented compounds for the perfumery and cosmetics sectors.
Overall, the versatility of 1,2,4-triethoxybenzene stems from its solvent capabilities, low toxicity, and stability, making it a valuable component across different industrial applications.

InChI:InChI=1/C12H18O3/c1-4-13-10-7-8-11(14-5-2)12(9-10)15-6-3/h7-9H,4-6H2,1-3H3

Upstream product

• 533-73-3 1,2,4-Trihydroxybenzene 
• 75-03-6 ethyl iodide 
• 613-03-6 1,2,4-triacetoxybenzene 
• 927-80-0 1-ethoxyacetylene 
• 74-96-4 ethyl bromide 
• 124-38-9 carbon dioxide 
• 65383-59-7 3,4-diethoxyphenol 

Downstream Products

• 952018-22-3 1,2,4-triethoxy-5-bromo-benzene 
• 55403-58-2 1-nitro-2,4,5-triethoxybenzene 
• 67827-54-7 2,4,5-triethoxy-benzaldehyde 
• 55119-66-9 3-(2,4,5-Triaethoxybenzoyl)-trans-acrylsaeure 
• 63213-33-2 5-Oxo-5-(2,4,5-triethoxy-phenyl)-pentanoic acid 
• 63213-32-1 2-Methyl-4-oxo-4-(2,4,5-triethoxy-phenyl)-butyric acid 
• 63213-31-0 2,4,5-Triethoxybutyrophenon 
• 63213-27-4 4-[4-oxo-4-(2,4,5-triethoxy-phenyl)-butyryl]-morpholine 
• 63213-45-6 3-(2'-hydroxy-4',5'-diethoxybenzoyl)propionic acid 
• 41827-43-4 3-(2,4,5-Triaethoxybenzoyl)propionitril 
• 63213-34-3 3-(2,4,5-Triaethoxybenzoyl)brenztraubensaeure 
• 63213-44-5 2,4-Dioxo-4-(2,4,5-triethoxy-phenyl)-butyric acid ethyl ester 
• 17231-76-4 1-<2,4,5-Triaethoxyphenyl>-2-nitro-propen 
• 85258-98-6 5-(2,4,5-Triethoxy-phenyl)-thiazolidine-2,4-dione 

Relevant academic research and scientific papers

Reactions of alkynes with [RuCl(cyclopentadienyl)] complexes: The important first steps

Cyclopentadienyl-ruthenium half-sandwich complexes with η2-bound alkyne ligands have been suggested as catalytic intermediates in the early stages of Ru-catalyzed reactions with alkynes. We show that electronically unsaturated complexes of the formula [RuCl(Cp)(η2-RC=CR')] can be stabilized and crystallized by using the sterically demanding cyclopentadienyl ligand Cp (Cp = η5-l-methoxy-2,4tert-butyl-3-neopentyl-cyclopentadienyl). Furthermore we demonstrate that [RuCl2(Cp)]2 is an active and regioselective catalyst for the [2+2+2] cyclotrimerization of alkynes. The first elementary steps of the reaction of mono(η2- alkyne) complexes containing {RuCl(Cp*)} (Cp* = η5- C5Me5) and (RuCl(Cp)} fragments with alkynes were investigated by DFT calculations at the M06/6-31G* level in combination with a continuum solvent model. Theoretical results are able to rationalize and complement the experimental findings. The presence of the sterically demanding Cp ligand increases the activation energy required for the formation of the corresponding di(η2alkyne) complexes, enhancing the initial regioselectivity, but avoiding the evolution of the system towards the expected cyclotrimerization product when bulky substituents are present. Theoretical results also show that the electronic structure and stability of a metallacyclic intermediate is strongly dependent on the nature of the substituents present in the alkyne.

NICKEL(0)-CATALYZED CYCLOADDITION OF ETHOXYETHYNE WITH CARBON DIOXIDE TO 4,5-DIETHOXY-α-PYRONE

Ni(0)-phosphine(L) complexes (L=tri-n-alkylphosphines and bis(diphenylphosphino)butane) catalyzed the cycloaddition of ethoxyethyne and carbon dioxide to afford 4,5-diethoxy-α-pyrone regioseletively.