41855-95-2Relevant academic research and scientific papers
NHC-Catalyzed Aza-Benzoin Condensation of N, N′-Dipyridin-2-yl Aminals with Aldehydes
Lamb, Justin S.,Takashima, Ryo,Suzuki, Yumiko
, p. 10224 - 10234 (2021/08/16)
α-Amino ketones are useful compounds because of their synthetic utility and bioactivities. After observing the ability of N,N′-dipyridin-2-yl aminals to form imines in situ, the synthesis of α-amino ketones using N,N′-dipyridin-2-yl aminals was proposed.
NEW SYNTHETIC METHODOLOGY FOR THE PREPARATION OF SUBSTITUTED 1-ARYL-1-PYRIDYLAMINOMETHANEPHOSPHONIC ACID ESTERS
Burkhouse, David W.,Zimmer, Hans
, p. 1437 - 1448 (2007/10/02)
Esters of 1-phenyl-1-pyridylaminomethanephosphonates generally cannot, or only in poor yields be prepared by the usual methods by treatment of the appropriate Schiff base with diethyl or diphenyl phosphite.However, it was found that these phosphonates are
CONDENSATION REACTIONS BETWEEN AROMATIC ALDEHYDES AND SOME HETEROCYCLIC AROMATIC AMINES
Forlani, Luciano,Sintoni, Marina,Todesco, Paolo E.
, p. 229 - 232 (2007/10/02)
1,1-Diamino derivatives are obtained by means of reactions between 2-aminothiazole and aromatic aldehydes carried out in methanol (and in dimethyl sulphoxide).The reaction of amine with the C=N of imine occurs without catalyst and is an easier process than its addition to C=O.This behaviour is also displayed by a number of aromatic heterocycles and homocyclic amines and may be explained by considering the activating effect of the electron-withdrawing group present in the imine moiety.
Kinetics and Mechanism of Hydrolysis of Bis(N-2-aminopyridyl)phenylmethane
Dash, Anadi C.,Patra, Moheswar,Dash, Bhaskar,Mahapatra, Prasanna K.
, p. 944 - 947 (2007/10/02)
The hydrolysis of bis(N-2-aminopyridyl)phenylmethane involves consecutive reactions, first step being its transformation to the N-benzylidene-2-aminopyridine schiff base followed by the hydrolysis of the schiff base to the end products.The kinetic data for both the steps are reported at 35 deg C, I = 0.1 mol dm-3 in aq. methanol (50 percent, v/v).
