1883-96-1

Basic information

• Product Name: N-[(E)-phenylmethylidene]pyridin-2-amine
• Synonyms: 2-Pyridinamine, N-(phenylmethylene)-; 2-pyridinamine, N-[(1E)-phenylmethylene]-; N-(Phenylmethylene)-2-pyridinamine; N-[(E)-Phenylmethylene]pyridin-2-amine
• CAS NO: 1883-96-1
• Molecular Formula: C₁₂H₁₀N₂
• Molecular Weight: 182.2212
• Mol File: 1883-96-1.mol
• Article Data: 50

Chemical Properties

• Boiling Point: 324.162°C at 760 mmHg
• Flash Point: 149.848°C
• Density: 1.023g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.575
• CAS DataBase Reference: N-[(E)-phenylmethylidene]pyridin-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(E)-phenylmethylidene]pyridin-2-amine(1883-96-1)
• EPA Substance Registry System: N-[(E)-phenylmethylidene]pyridin-2-amine(1883-96-1)

Safety Data

• Hazardous Substances Data: 1883-96-1(Hazardous Substances Data)

Upstream product

• 41855-95-2 N,N¹--α,α-diaminotoluene 
• 71-43-2 benzene 
• 504-29-0 2-aminopyridine 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 108-93-0 cyclohexanol 
• 108-88-3 toluene 
• 23574-81-4 N-(triphenylphosphoranylidene)pyridin-2-amine 
• 538-51-2 benzylidene phenylamine 
• 27200-79-9 p-bromophenylacetaldehyde 

Downstream Products

• 64138-49-4 N-(1-phenylethyl)pyridin-2-ylamine 
• 93725-14-5 N,N-dimethyl-N'-(1-phenyl-ethyl)-N'-[2]pyridyl-ethylenediamine 
• 96354-74-4 N-(diphenylmethyl)pyridin-2-amine 
• 74037-48-2 N-(1,2-diphenylethyl)pyridin-2-amine 
• 54214-70-9 2,3-diphenyl-4H-pyrido[1,2-a]pyrimidin-4-one 
• 59046-00-3 3-chloro-2-phenylpyrido<1,2-a>pyrimidin-4(4H)-one 
• 91538-37-3 3,3-dichloro-4-phenyl-1-(2-pyridyl)-2-azetidinone 
• 91538-38-4 methyl 2,2-dichloro-3-phenyl-3-(2-pyridylamino)propanoate 
• 159639-04-0 4,4-dimethyl-1-phenyl-1-(pyridin-2-yl)aminopropan-3-one 
• 91538-35-1 2,2-dichloro-3-phenyl-3-(2-pyridylamino)propanoic acid 
• 64413-91-8 2-phenyl-3-chloroimidazo<1,2-a>pyridine 
• 4044-95-5 2-Phenyl-3-bromoimidazo<1,2-a>pyridine 
• 138023-19-5 2-pyridine 
• 122053-39-8 [Phenyl-(pyridin-2-ylamino)-methyl]-phosphonic acid diphenyl ester 

Relevant articles and documents

Study of N-benzylidene derivatives synthesized as corrosion inhibitors for copper in HCl solution

Corrosion inhibition of the two N-benzylidene derivative compounds, namely N-benzylidene pyridin-2 amine (NBPA) and N-(4-choloromethylbenzylidene) pyridin-2 amine (NCMBPA) as corrosion inhibitors for copper in hydrochloric acid 6.0 M have been studied by

Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions

The reaction of [RuCl2(p-cymene)]2 with in situ prepared Ag-N-heterocyclic carbene (NHC) complexes yields a series of [RuCl2(p-cymene)(NHC)] complexes (2). All of the complexes have been characterised by elemental analysis, and 1H NMR and 13C NMR spectroscopies. These complexes have been tested for the N-alkylation of aromatic amines with arylmethyl alcohols under neat conditions in the presence of KOtBu at 120 °C. Compounds (2) are stable and have high catalytic/selective activity for the N-alkylation reactions of primary amines to afford secondary amines.

Luminescent coatings: White-color luminescence from a simple and single chromophore with high anticorrosion efficiency

Luminescent coatings have potential commercial applications. Here, the photoluminescence, thermal, and corrosion inhibition properties of reported Schiff bases have been studied. Moreover, quantum chemical calculations have been done to realize the working mechanism of their properties. Interestingly, we succeeded to get a single-chromophore white-color emission from a small Schiff base molecule through a simple technique, where the relative emission intensities at the long and short wavelengths of the visible range were controlled by introducing electron-donating or withdrawing groups. Furthermore, the compounds were found thermally stable and can emit efficiently until 124 °C. Also, the electrochemical impedance spectroscopy, electrochemical frequency modulation, Tafel polarization, and surface characterizations have been investigated. The studied compounds showed high inhibition efficiencies (ex. 93%) and played a great role in retarding the stainless-steel corrosion in 2 M H2SO4. These measurements confirmed that the existence of these Schiff bases can reduce the double-layer capacities, corrosion current densities, and corrosion rate simultaneously with increasing the charge transfer resistance values. The studied materials as luminescent coatings may be employed for mixed-type inhibitors and can provide a strategy for the development of new organic materials capable of producing white-color emission from a simple and single molecule.