41997-32-4Relevant articles and documents
Slow reversible inhibitions of rabbit muscle aldolase with substrate analogues: Synthesis, enzymatic kinetics and UV difference spectroscopy studies
Gefflaut,Blonski,Perie
, p. 2043 - 2054 (2007/10/03)
Various dihydroxyacetone-phosphate (DHAP) analogues bearing an aromatic ring or β-dicarbonyl structures were synthesized. Their capacity to form a stabilized iminium ion or conjugated enamine in the reaction catalyzed by rabbit muscle aldolase (EC 4.1.2.1
Synthesis of β-keto-phosphotriesters using functionalized diazoketones
Gefflaut,Perie
, p. 29 - 33 (2007/10/02)
Convenient substitution (Ac) on the heteroatom in diazo ketones as in compounds 6, 8 or 10, prevents the classical cyclisation reaction and allows intermolecular addition; the reaction is applied to phosphorylation (reaction 1).
STUDIES ON OXYGEN HETEROCYCLES PART-1 : ACID CATALYSED AND PHOTOCHEMICAL REACTIONS OF SOME ARYLDIAZOKETONES
Ghosh, Somnath,Datta, Indira,Chakraborty, Rupak,Das, Tapas Kumar,Sengupta, Judhajit,Sarkar, Dipak Chandra
, p. 1441 - 1446 (2007/10/02)
Trifluoroacetic acid catalysed reaction of 2-methoxyphenyldiazomethylketone (4a), 2-acetoxyphenyldiazomethylketone (4b) and 3-(2-anisyl)-α-diazo-2-propanone (11) leads to the formation of coumaranone (6) and 3-chromanone (12), while 4-(2-anisyl)-α-diazo-2-butanone (16) affords benzo-1-oxepan-3-one (17) and 5-methoxy-2-tetralone (18) in moderate yield.The photochemical decomposition of the said diazoketones (4a, 11 and 16) gave products depending on the length of the side chain present in the substrates.
