154470-10-7Relevant academic research and scientific papers
Synthesis of β-keto-phosphotriesters using functionalized diazoketones
Gefflaut,Perie
, p. 29 - 33 (1994)
Convenient substitution (Ac) on the heteroatom in diazo ketones as in compounds 6, 8 or 10, prevents the classical cyclisation reaction and allows intermolecular addition; the reaction is applied to phosphorylation (reaction 1).
Slow reversible inhibitions of rabbit muscle aldolase with substrate analogues: Synthesis, enzymatic kinetics and UV difference spectroscopy studies
Gefflaut,Blonski,Perie
, p. 2043 - 2054 (2007/10/03)
Various dihydroxyacetone-phosphate (DHAP) analogues bearing an aromatic ring or β-dicarbonyl structures were synthesized. Their capacity to form a stabilized iminium ion or conjugated enamine in the reaction catalyzed by rabbit muscle aldolase (EC 4.1.2.1
