422-55-9Relevant academic research and scientific papers
PROCESS FOR PRODUCING 1, 1-DICHLORO-2, 2, 3, 3, 3-PENTAFLUOROPROPANE
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Page/Page column 4-5, (2012/01/14)
To provide a process for producing, at a high content ratio, 1,1-dichloro-2,2,3,3,3-pentafluoropropane (HCFC-225ca) which is useful as e.g. a starting material to obtain 1,1-dichloro-2,3,3,3-tetrafluoropropene (CFO1214ya). The process for producing HCFC-225ca of the present invention comprises subjecting a raw material composed of dichloropentafluoropropane (HCFC-225) including 2,2-dichloro-1,1,1,3,3-pentafluoropropane (HCFC225aa) to an isomerization reaction at a temperature of at most 290° C. in a gas phase in the presence of a metal oxide catalyst thereby to isomerize HCFC-225aa to HCFC-225ca.
Catalytical production processes for making hydrohalopropanes and hydrofluorobutanes
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Page/Page column 4, (2008/06/13)
A process is disclosed for making hydrohalopropanes or hydrofluorobutanes. The process involves reacting a hydrofluoromethane with a fluoroolefin in the presence of an aluminum catalyst to produce a hydrohalopropane or a hydrofluorobutane. The hydrofluoromethane is CH2F2 or CH3F. The fluoroolefin is CF2═CF2, ClFC═CF2, or CF3CF═CF2.
PYROLYSIS PROCESS
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Page/Page column 4-5, (2008/06/13)
The present invention relates to the pyrolysis of hydrochlorofluorocarbons to form fluoromonomers such as tetrafluoroethylene, the pyrolysis being carried out in a reaction zone lined with nickel and mechanically supported by a jacket of other corrosion resistant metal, the nickel lining providing an improved yield of valuable reaction products.
19F nuclear magnetic resonance studies of halogenated propanes
Tanuma, T.,Ohnishi, K.,Okamoto, H.,Miyajima, T.,Morikawa, S.
, p. 259 - 284 (2007/10/02)
The relationship between 19F chemical shifts in halogenated propanes and their structures are elucidated using MNDO calculations to determine the population of rotamers.The pairs of atom gauche to a fluorine atom and van der Waals interaction between the two terminal substituents are responsible for the 19F chemical shifts.The differences among chemical shifts in diastereomers are also discussed in terms of the conformation of molecule.
