422-77-5Relevant academic research and scientific papers
Addition of some unreactive fluoroalkanes to tetrafluoroethylene.: Direct catalytic synthesis of F-butene-2
Petrov, Viacheslav A.,Krespan, Carl G.
, p. 199 - 204 (2007/10/03)
Condensation of trifluoromethanes, CF3X (X=H, Cl, Br, I), with tetrafluorethylene to form the corresponding F-n-propyl adducts have been carried out with aluminum chlorofluoride as catalyst. Yields of C3F7I and C3F7Br are especially good, making these useful perfluoropropyl intermediates readily available. Details of the reactions, especially the presence of low percentages of perfluoroisopropyl iodide and bromide in the products, are accounted for by proposed mechanisms involving halonium intermediates. Longer-chain primary iodides can also be added to tetrafluoroethylene, but the final products are predominantly fluoroolefins, with pentafluoroethyl iodide as a byproduct. In the case of the addition of C2F5I to tetrafluoroethylene, conditions for an efficient, low temperature dimerization of terafluoroethylene to F-butene-2 catalyzed by a combination of C2F5I/aluminum chlorofluoride have been defined. Evidence for an unusual transfer of I+ from the iodonium derivative of F-butene-2 to tetrafluoroethylene is presented.
Pyrolysis of branched-chain perfluoroalkanes in the presence of halogens
Tonelli, Claudio,Tortelli, Vito
, p. 125 - 128 (2007/10/03)
The thermal decomposition of some highly branched perfluoroalkanes in the presence of molecular halogens (Cl2, Br2, I2) has been studied.The clear-cut cleavage of the most hindered carbon-carbon bond and the trapping by halogens of the intermediate radicals so formed account for the product distribution.Kinetic measurements support a mechanism based on homolytic rupture of the perfluoroalkanes as the rate-determining step, followed by the fast reaction of the intermediates with halogens.
