42201-34-3Relevant academic research and scientific papers
Indium-mediated regioselective Markovnikov allylation of unactivated terminal alkynes
Ranu, Brindaban C.,Majee, Adinath
, p. 1225 - 1226 (2007/10/03)
Allylation of unactivated terminal alkynes by a simple treatment with allyl bromide and indium metal in THF at room temperature produces 1,4-dienes via regioselecttve Marknovnikov addition.
Formation of a New Bis-Organocopper Reagent from the Reaction of 2,3-Dichloropropene and Highly Active Zero Valent Copper Derived from a CuCN*2LiCl Complex
Stack, Douglas E.,Rieke, Reuben D.
, p. 6575 - 6578 (2007/10/02)
Highly reactive zero valent copper derived from a CuCN*2LiCl complex reacts directly with 2,3-dichloropropene to yield a new bis-organocopper species containing both a nucleophilic allylic and vinylic moiety.This new bis-organocopper reagent undergoes selective one-pot addition to two different electrophiles in good to excellent yields.
