42205-96-9Relevant articles and documents
Visible-Light Induced Direct Synthesis of Polysubstituted Furans from Cyclopropyl Ketones
Feng, Liyan,Yan, Hang,Yang, Chao,Chen, Dafa,Xia, Wujiong
, p. 7008 - 7022 (2016/08/30)
In this article, a photoredox protocol for the synthesis of furans via oxidative coupling of olefin generated in situ from cyclopropyl ketones with ketonic oxygen atom is presented. Moreover, bromination of furans in the presence of overstoichiometric oxidant has been achieved with high regioselectivity.
Further Investigations into the Mechanism of the Acid Catalysed Rearrangement of Aryl Substituted Cyclopropyl Ketones
Hantawong, Kesra,Murphy, William S.
, p. 2520 - 2547 (2007/10/02)
The acid catalysed rearrangement of a number of aryl cyclopropyl ketones (2) to tetralones (3) were investigated in situ by 1H and 13C n.m.r. spectroscopy.The formation of oxycyclopentenyl intermediates (4) were observed.The involvement of a concurrent el