42492-96-6Relevant academic research and scientific papers
One-pot synthesis of α-aminonitriles from alkyl and aryl cyanides: a Strecker reaction via aldimine alanes
Sipos, Szabolcs,Jablonkai, István
experimental part, p. 1844 - 1846 (2009/07/17)
A one-pot Strecker reaction using various alkyl, arylalkyl and arylnitriles is developed. Aldimine alanes were generated in situ from nitriles by the addition of diisobutylaluminium hydride, and were converted into the corresponding imines on reaction wit
Asymmetric Syntheses of Amino Acids by Addition of Cyanide to the Schiff Bases in the Presence of Cyanide-Modified Hemin-Copolymer
Saito, Kiyoshi,Harada, Kaoru
, p. 4535 - 4538 (2007/10/02)
Sterically controlled addition reactions of CN group to the Schiff bases by using CN-modified hemin-copolymer were carried out, and the optical yields (80-95 e.e.) of the resulting amino acids were much higher than that obtained without hemin-copolymer.
