426233-44-5Relevant academic research and scientific papers
Iodine-promoted one-pot synthesis of 1,3,4-oxadiazole scaffolds: Via sp3 C-H functionalization of azaarenes
Mani, Geeta Sai,Donthiboina, Kavitha,Shankaraiah, Nagula,Kamal, Ahmed
, p. 15999 - 16006 (2019)
An efficient iodine-mediated one-pot synthetic protocol for the synthesis of 2,5-disubstituted 1,3,4-oxadiazole scaffolds has been developed via sp3 C-H functionalization. Gratifyingly, this method involves oxidative amination with concomitant base-mediated cyclization of methylhetarenes and acylhydrazines by employing iodine and Cs2CO3. The key features of the present method include good functional group tolerance, a clean protocol, metal-free conditions and high yields, making this protocol an attractive strategy towards the synthesis of bioactive molecules and their key building blocks.
Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation
Amorim, André L.,Bregalda, Mayana B.,Camargo, Tiago P.,De Souza, Bernardo,Farias, Giliandro,Haukka, Matti,Nordlander, Ebbe,Peralta, Rosely A.,Weiss, Vitor C.,Xavier, Fernando R.
, p. 13078 - 13090 (2020/10/09)
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculati
