42817-30-1Relevant articles and documents
CONVENIENT PREPARATION OF CYCLO-EICOSASULPHUR (S20) FROM BIS(η-CYCLOPENTADIENYL)(PENTASULPHIDO)TITANIUM(IV)
Steudel, Ralf,Strauss, Reinhard
, p. 1775 - 1778 (2007/10/02)
High-pressure liquid chromatographic analysis of stoicheiometric mixtures of (cp=η-cyclopentadienyl) and SO2Cl2 in CS2 solution has revealed the presence of S10, S15, S20, and S25 in order of decreasing concentration.The compound S20 has been isolated in 8percent yield and a reaction mechanism explaining its formation is proposed.An improved synthesis (88percent yield) of from is also reported.