42855-49-2

Upstream product

• 603-35-0 triphenylphosphine 
• 98-83-9 isopropenylbenzene 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 98-86-2 acetophenone 

Downstream Products

• 84313-11-1 3-(2-Furyl)-1,4-diphenyl-4-<(E)-2-(2-furyl)ethenyl>-1-cyclohexen 
• 84313-23-5 (Z)-1-(2-Furyl)-3-phenyl-1,3-butadien 
• 84313-22-4 (Z)-3-Phenyl-1-(2-thienyl)-1,3-butadien 
• 73349-15-2 (3Z)-2-phenyl-1,3-octadiene 
• 84313-28-0 (Z)-1-(2,2-Diphenylcyclopropyl)-3-phenyl-1,3-butadien 
• 84384-06-5 (1-E,3-Z)-1,5-Diphenyl-<2-D>-1,3,5-hexatrien 
• 84313-02-0 3-(4-Methylphenyl)-4-<(E)-2-(4-methylphenyl)ethenyl>-1,4-diphenyl-1-cyclohexen 
• 84313-18-8 (Z)-1-(4-Methylphenyl)-3-phenyl-1,3-butadien 
• 84313-04-2 3-(4-Chlorphenyl)-4-<(E)-2-(4-chlorphenyl)ethenyl>-1,4-diphenyl-1-cyclohexen 
• 84313-17-7 (Z)-1-(4-Chlorphenyl)-3-phenyl-1,3-butadien 
• 84313-06-4 3-(4-Methoxyphenyl)-4-<(E)-2-(4-methoxyphenyl)ethenyl>-1,4-diphenyl-1-cyclohexen 
• 84313-21-3 1-Nitro-4-((Z)-3-phenyl-buta-1,3-dienyl)-benzene 
• 1082717-50-7 1,3,4-Triphenyl-4-<(E)-styryl>-1-cyclohexen 
• 21035-05-2 [(Z)-3-phenylbuta-1,3-dien-1-yl]benzene 

Relevant academic research and scientific papers

Chiral Br?nsted Acid Catalyzed Dynamic Kinetic Asymmetric Hydroamination of Racemic Allenes and Asymmetric Hydroamination of Dienes

The first highly efficient and practical chiral Br?nsted acid catalyzed dynamic kinetic asymmetric hydroamination (DyKAH) of racemic allenes and asymmetric hydroamination of unactivated dienes with both high E/Z selectivity and enantioselectivity are described herein. The transformation proceeds through a new catalytic asymmetric model involving a highly reactive π-allylic carbocationic intermediate, generated from racemic allenes or dienes through a proton transfer mediated by an activating/directing thiourea group. This method affords expedient access to structurally diverse enantioenriched, potentially bioactive alkenyl-containing aza-heterocycles and bicyclic aza-heterocycles.

Highly-functionalized arene synthesis based on palladium on carbon-catalyzed aqueous dehydrogenation of cyclohexadienes and cyclohexenes

Transition metal-catalyzed dehydrogenation is a clean oxidation method requiring no additional oxidants. We have accomplished a heterogeneous Pd/C-catalyzed aqueous dehydrogenation of 1,4-cyclohexadienes and cyclohexenes to give the corresponding highly-functionalized arenes. Furthermore, various arenes could be efficiently constructed in a one-pot manner via a Diels-Alder reaction and the following dehydrogenation.

Palladium-catalyzed silylene-1,3-diene [4 + 1] cycloaddition with use of (aminosilyl)boronic esters as synthetic equivalents of silylene

(Chemical Equation Presented) Silylboronic esters bearing a dialkylamino group on the silicon atoms reacted with 1,3-dienes in the presence of a palladium catalyst to give silacyclopent-3-enes (i.e., 2,5-dihydrosiloles) in high yields via efficient silyle

Synthesis of Isomerically Pure (E)- and (Z)-1,3-Disubstituted 1,3-Dienes

The (E)-dienes 1a - p were prepared in >98percent purity by dehydrative decarboxylation of the corresponding 4,5-unsaturated 3-hydroxycarboxylic acids 3 with dimethylformamide dimethylacetal (11).The (Z)-isomers 6a - m were obtained by stereouncontrolled