42966-62-1

Basic information

• Product Name: Cyclohexanamine, N-(1-methylpropyl)-
• CAS NO: 42966-62-1
• Molecular Formula: C10H21N
• Molecular Weight: 155.283
• Mol File: 42966-62-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanamine, N-(1-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanamine, N-(1-methylpropyl)-(42966-62-1)
• EPA Substance Registry System: Cyclohexanamine, N-(1-methylpropyl)-(42966-62-1)

Safety Data

• Hazardous Substances Data: 42966-62-1(Hazardous Substances Data)

Upstream product

• 98-95-3 nitrobenzene 
• 78-92-2 iso-butanol 
• 108-91-8 cyclohexylamine 
• 78-93-3 butanone 
• 6125-75-3 N-cyclohexylbutylidene-2-imine 
• 86024-88-6 3-cyclohexylamino-1-butyne 

Downstream Products

• 83918-30-3 sec-Butyl-(2-chloro-ethyl)-cyclohexyl-amine 
• 118699-83-5 5-(N-cyclohexyl-N-s-butyl)aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 83918-28-9 2-(sec-Butyl-cyclohexyl-amino)-ethanol 
• 57375-74-3 N-Isopropoxycarbonyl-3-(N-sec.-butyl-cyclohexylcarbamoyloxy)anilin 
• 854913-34-1 sec-butyl-cyclohexyl-methyl-amine 

Relevant articles and documents

Highly efficient one-pot multi-directional selective hydrogenation and N-alkylation catalyzed by Ru/LDH under mild conditions

Atomic economy, non-toxicity, harmlessness and multidirectional selectivity advocated by green chemistry have increasingly become a hot and difficult research topic. Herein, we present a highly efficient, one-pot tandem and easy-to-operate method through which we could directly produce a broad range of multi-directional selective hydrogenated amines or N-alkyl aliphatic amines using aromatic nitro compounds as raw materials. Ru/LDH with characteristics of layered mesoporous structure, well dispersed small Ru nanoparticles and LDH stabilization to the Ru NPs was employed as the catalyst. It is remarkable that multi-directional superb chemoselectivity to aromatic amines, alicyclic amines as well as N-alkyl aliphatic amines could be achieved with excellent catalytic activity and recyclability by tuning reaction conditions over 5wt%Ru/LDH-2. Additionally, this catalytic system also exhibited attractive activity and multi-directional chemoselectivity in the hydrogenation of quinoline and its derivatives with solvents of different polarity. Chemoselectivity to 5,6,7,8-tetrahydroquinoline derivatives could reach as high as 95.6 %.

Selective Deoxygenation of Various N-O Bonds Catalyzed by Rhodium Carbonyl Clusters in the Presence of H2O and CO and Their Heterogenization Using Amino-Substituted Polystyrenes

Catalytic deoxygenation of various N-O bonds using rhodium carbonyl compounds under a water gas shift reaction was studied.A catalyst system of Rh6(CO)16 and N,N,N',N'-tetramethyl-1,3-propanediamine was found to have high activities for the following deoxygenations: 1) conversion of nitrobenzenes to anilines, 2) aliphatic nitro compounds to nitriles, 3) oximes to nitriles, 4) hydroxylamines to amines, and 5) amine oxides to amines.The above-mentioned rhodium catalyst system was heterogenized by using amino-substituted polystyrenes.Rh6 and Rh14 carbonyl clusters of -, 2-, and 4-, were formed on the polymer surface.The characteristic features of the catalysis of the polymer-bound rhodium cluster complexes are described in relation to the corresponding homogenous ones.