42967-53-3

Basic information

• Product Name: tetraphenylbismuthonium chloride
• Synonyms: tetraphenylbismuthonium chloride
• CAS NO: 42967-53-3
• Molecular Weight: 552.856
• Mol File: 42967-53-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetraphenylbismuthonium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: tetraphenylbismuthonium chloride(42967-53-3)
• EPA Substance Registry System: tetraphenylbismuthonium chloride(42967-53-3)

Safety Data

• Hazardous Substances Data: 42967-53-3(Hazardous Substances Data)

Upstream product

• 7647-01-0 hydrogenchloride 
• 3049-07-8 pentaphenylbismuth 
• 101359-08-4 N-tosyltriphenylbismuthimine 

Downstream Products

• 603-33-8 triphenylbismuthane 
• 108-90-7 chlorobenzene 
• 43047-28-5 tetraphenylbismuthonium perchlorate 
• 58593-03-6 {(C₆H₅)4Bi}⁽¹⁺⁾*(C₆H₅)3SiO^(1-)={(C₆H₅)4Bi}OSi(C₆H₅)3 
• 28719-55-3 triphenylbismuth dibromide 
• 39248-62-9 diphenylbismuthanyl bromide 
• 66173-02-2 tetraphenylbismuth bromide 
• 6782-04-3 tetraphenylbismuthonium tetraphenylborate 
• 38589-85-4 tetraphenylbismuthonium nitrate 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 
• 98-95-3 nitrobenzene 
• 38589-86-5 tetraphenybismuthonium trichloroacetate 
• 3049-07-8 pentaphenylbismuth 

Relevant articles and documents

Tetraphenylbismuth(V) Derivatives Ph4BiCl, [Ph4BiDMSO-O][PtBr3DMSO-S] and [Ph4Bi]2[PtCl6]: Synthesis and Structure

Abstract: The product of the reaction between tetraphenylbismuth chloride Ph4BiCl (I) synthesized via the dephenylation of pentaphenylbismuth with hydrochloric acid and potassium hexabromoplatinate (2 : 1 mol/mol) in water after recrystallization from dimethylsulfoxide is О-dimethylsulfoxydotetraphenylbismuth S-dimethylsulfoxidotribromoplatinate [Ph4BiDMSO-O][PtBr3DMSO-S] (II). Recrystallization of the complex synthesized from compound I and potassium hexachloroplatinate from acetonitrile gives tetraphenylbismuth hexachloroplatinate [Ph4Bi]2[PtCl6] (III). Structures I–III have been studied by X-ray diffraction. The coordination polyhedron of bismuth atoms in compounds I and II (a crystal contains two types of crystallographically independent ions) is a distorted trigonal bipyramid with heteroatoms in axial positions, and the CBiCl and CBiО axial angles are 175.8(1)°, 177.4(3)°, and 177.3(4)°, respectively; the Bi–Cl distances are 2.912(2) ? (I), and Bi–О is 2.78(1) and 2.76(1) ? (II); in the equatorial plane, the Bi–C bonds and the CBiC angles are, respectively, 2.204(4)–2.224(4) ? and 113.42(16)°–123.35(15)° in I, 2.170(13)–2.181(12) ?, 2.155(12)–2.187(13) ? and 110.9(4)°–123.8(4)°, 111.0(4)°–123.3(5)° in II. The cation in structure III is a distorted tetrahedron, Bi–C bonds vary within a range of 2.199(4)–2.231(4) ?, and the CBiC angles are 102.6(2)°–126.5(2)°. The platinum atoms in the anions of compound II are tetracoordinated, the trans-BrPtBr and trans-SPtBr angles are ranged within 176.51(11)°–177.62(6)°; the Pt–Br bonds are 2.402(3)–2.424(3) ?, and the Pt–S distances are 2.200(4) and 2.182(4) ?. In the centrosymmetric octahedral anions of compound III, the trans-ClPtCl angles are 180°, and the cis-ClPtCl angles are 88.71(6)°–91.29(6)°; the Pt–Cl bonds are 2.329(2)–2.3350(18) ?.