429680-15-9Relevant academic research and scientific papers
An unusual ruthenium-catalyzed cycloisomerization of alkynes and propargyl alcohols
Trost, Barry M.,Rudd, Michael T.
, p. 4178 - 4179 (2002)
CpRu(NCCH3)3+PF6- catalyzes the cycloisomerization of diyne-ols to α,β,γ,δ-unsaturated aldehydes and ketones in good-to-excellent yields. 1-Hydroxy-2,7-diynes and 1-hydroxy-2,8-diynes can be utilized to form hig
Ruthenium-catalyzed cycloisomerizations of diynols
Trost, Barry M.,Rudd, Michael T.
, p. 4763 - 4776 (2007/10/03)
A wide variety of diynols containing tertiary, secondary, and primary propargylic alcohols undergo a cycloisomerization reaction to form dienones and dienals in the presence of a catalytic amount of [CpRu(CH3CN) 3]PF6. The
