429680-16-0Relevant academic research and scientific papers
Ruthenium-catalyzed cycloisomerization-6π-cyclization: A novel route to pyridines
Trost, Barry M.,Gutierrez, Alicia C.
, p. 1473 - 1476 (2008/02/02)
Equation presented Herein we report a method for the synthesis of substituted pyridines. The unsaturated ketones and aldehydes derived from the cycloisomerization of primary and secondary propargyl diynols in the presence of [CpRu (CH3CN)3
Ruthenium-catalyzed cycloisomerizations of diynols
Trost, Barry M.,Rudd, Michael T.
, p. 4763 - 4776 (2007/10/03)
A wide variety of diynols containing tertiary, secondary, and primary propargylic alcohols undergo a cycloisomerization reaction to form dienones and dienals in the presence of a catalytic amount of [CpRu(CH3CN) 3]PF6. The
An unusual ruthenium-catalyzed cycloisomerization of alkynes and propargyl alcohols
Trost, Barry M.,Rudd, Michael T.
, p. 4178 - 4179 (2007/10/03)
CpRu(NCCH3)3+PF6- catalyzes the cycloisomerization of diyne-ols to α,β,γ,δ-unsaturated aldehydes and ketones in good-to-excellent yields. 1-Hydroxy-2,7-diynes and 1-hydroxy-2,8-diynes can be utilized to form hig
