43087-42-9

Basic information

• Product Name: 4-methoxy-1,2-dimethyl-1,4-cyclohexadiene
• Synonyms: 4-methoxy-1,2-dimethyl-1,4-cyclohexadiene
• CAS NO: 43087-42-9
• Molecular Weight: 138.21
• Mol File: 43087-42-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-methoxy-1,2-dimethyl-1,4-cyclohexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-1,2-dimethyl-1,4-cyclohexadiene(43087-42-9)
• EPA Substance Registry System: 4-methoxy-1,2-dimethyl-1,4-cyclohexadiene(43087-42-9)

Safety Data

• Hazardous Substances Data: 43087-42-9(Hazardous Substances Data)

Upstream product

• 4685-47-6 3,4-dimethylanisole 
• 67-56-1 methanol 
• 7664-41-7 ammonia 

Downstream Products

• 53829-24-6 1,2-dimethyl-1-cyclohexen-4-yl tosylate 
• 53829-23-5 3,4-dimethylcyclohex-3-enol 
• 33475-09-1 1,2-dimethyl-1-cyclohexen-4-one 
• 43087-41-8 1-Methoxy-3,4-dimethylcyclohexa-1,3-dien 
• 10463-42-0 3,4-dimethyl-cyclohex-2-enone 

Relevant articles and documents

Factors Influencing Conformational Preferences in Cyclohexenes

Conformational preferences have been measured for the first time for 4-substituted cyclohexenes in a solvent of low polarity.Measurements were made for the substituents Cl, Br, I, OH, OSiMe3, and CN and were compared with conformational preferences in cyclohexyl and exo-methylenecyclohex-3-yl.In the nearly nonpolar solvent CF2Cl2, in which intramolecular interactions are maximized, there is a much larger axial population for cyclohexen-4-yl than in cyclohexyl or exo-methylenecyclohex-3-yl.In particular, the dipolar interaction of the endocyclic double bond is reduced from that of the exocyclic double bond.This observation is confirmed by the almost negligible effect of symmetrizing the endocyclic double bond through 1,2-dimethyl substitution, in contrast with the large effect of symmetrizing the exocyclic double bond through 7,7-dimethyl substitution.Polar solvents increase the proportion of the axial conformer to a smaller extent for the endocyclic than for the exocyclic system, again in agreement with a lower dipolar effect in the endocyclic case.These results emphasize the anisotropic nature of the steric effects of double bonds.