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N,N-Dimethylcarbamic acid fluoride, also known as dimethylamine fluoride or DMF, is an organofluorine compound with the chemical formula C3H7FNO. It is a colorless, volatile liquid that is soluble in water and organic solvents. N,N-Dimethylcarbamic acid fluoride is primarily used as a reagent in organic synthesis, particularly in the preparation of various pharmaceuticals, agrochemicals, and other fluorinated compounds. DMF is known for its ability to act as a source of the fluoromethyl group in chemical reactions, making it a valuable building block in the synthesis of complex molecules. It is also used as a catalyst in certain reactions due to its ability to form stable intermediates. The compound is produced industrially through the reaction of dimethylamine with carbonyl fluoride or other fluorinating agents. Handling of N,N-Dimethylcarbamic acid fluoride requires caution due to its potential toxicity and reactivity, and it is typically stored under anhydrous conditions to prevent hydrolysis.

431-14-1

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431-14-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 431-14-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,3 and 1 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 431-14:
(5*4)+(4*3)+(3*1)+(2*1)+(1*4)=41
41 % 10 = 1
So 431-14-1 is a valid CAS Registry Number.
InChI:InChI=1/C3H6FNO/c1-5(2)3(4)6/h1-2H3

431-14-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name dimethyl-N-(fluoroformyl)amine

1.2 Other means of identification

Product number -
Other names N,N-dimethylfluoroformamide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:431-14-1 SDS

431-14-1Relevant academic research and scientific papers

REACTION OF TETRAKIS(DIMETHYLAMINO)ETHYLENE WITH CF2Br2 IN THE PRESENCE OF SECONDARY AMINES, FORMATION OF N-TRIFLUOROMETHYL-DIALKYLAMINES

Pawelke, G.

, p. 229 - 234 (1991)

N-trifluoromethylamines of the general formula R2NCF3 (R= Me (I), Et (II), i-Pr (III), i-Bu (IV); 2R = (CH3)2C-(CH2)3-C(CH3)2 (V) and (CH2)6 (VI)) have been obtained from the corresponding secondary amines R2NH with the reagent combination tetrakis(dimethylamino)ethylene/CF2Br2/(CH2)4SO2 in moderate yields.The new N-trifluoromethylamines have been characterized by elemental analyses, multinuclear NMR and vibrational spectra and the mechanism of formation is discussed.

The Combination of Potassium Fluoride and Calcium Fluoride: A Useful Heterogeneous Fluorinating Reagent

Ichihara, Junko,Matsuo, Toshiya,Hanafusa, Terukiyo,Ando, Takashi

, p. 793 - 794 (2007/10/02)

The combination of potassium fluoride and calcium fluoride was found to be an effective and practical solid reagent for the fluorination of various organic chlorides and bromides under mild conditions.

REACTIONS OF TERTIARY FORMAMIDES WITH SULPHUR TETRAFLUORIDE. DIRECT SYNTHESIS OF (TRIFLUOROMETHYL)AMINES

Dmowski, Wojciech,Kaminski, Maciej

, p. 207 - 218 (2007/10/02)

Treatment of dimethylformamide 1a, diethylformamide 1b, 1-formylpiperidine 3a, 4-formylmorpholine 3b, and ethyl-phenylformamide 5 with sulphur tetrafluoride in the presence of potassium fluoride resulted in a direct conversion of the formyl group to the t

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