4333-55-5

Upstream product

• 611-97-2 bis(p-methylphenyl)-methanone 
• 925-90-6 ethylmagnesium bromide 
• 768295-67-6 1,1-di-p-tolylpropan-1-ol 
• 56860-31-2 1,1-bis(p-methylphenyl)cyclopropane 
• 105-37-3 Ethyl propionate 
• 7789-89-1 1,1,1-trichloropropane 
• 108-88-3 toluene 
• 70671-90-8 1,1-dibromo-2,2-bis(4-methylphenyl)cyclopropane 
• 40938-15-6 4,4’-(propa-1,2-diene-1,1-diyl)bis(methylbenzene) 
• 22125-38-8 1,1-dichloro-2,2-bis(p-methylphenyl)cyclopropane 
• 2919-20-2 1,1-di(p-tolyl)ethylene 
• 82357-51-5 4,4'-(2-bromoprop-1-ene-1,1-diyl)bis(methylbenzene) 
• 74-85-1 ethene 
• 1143-91-5 bis(4-methylphenyl)diazomethane 

Downstream Products

• 106403-95-6 2-chloro-1,1-bis(p-methylphenyl)propene 
• 93407-42-2 1.1-Di--2-nitro-propanol-(1) 
• 94311-56-5 1-Acetoxy-1.1-di--2-nitro-propan 
• 82357-51-5 4,4'-(2-bromoprop-1-ene-1,1-diyl)bis(methylbenzene) 

Relevant academic research and scientific papers

Regioselective Diboron-Mediated Semireduction of Terminal Allenes

A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.

Metal-free Mizoroki-Heck type reaction: A radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins

An efficient metal-free Mizoroki-Heck type reaction of di- and tri-substituted alkenes with 2-chloro-dithiane has been developed under ambient pressure of air or using a relatively low loading of BF3·Et2O. This study represents a new environmentally friendly method for the syntheses of dithianyl-substituted alkene derivatives via a radical oxidative coupling process.

Arylcyclopropane Photochemistry. Effects of Electron-Donating and Electron-Withdrawing Aromatic Substituents on the Photochemical Rearrangements of 1,1-Diarylcyclopropanes.

Irradiation of 1,1-diarylcyclopropanes 4a-g, having substituents X and Y at the para positions of the aromatic rings, afforded 1,1-diarylpropenes 5a-g and 1-arylindans 6a-f.The rate constants of these (singlet state) reactions, determined from the reactan

ARYLCYCLOPROPANE PHOTOCHEMISTRY. SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL CONVERSION OF 1,1-DIARYLCYCLOPROPANES TO 1,1-DIARYLPROPENES AND 1-ARYLINDANES.

The rate of photochemical rearrangement of 1,1-diarylcyclopropanes to 1,1-diarylpropenes and 1-arylindanes is enhanced by electron-withdrawing groups on the aromatic rings and diminished by electron-donating groups.

A NOVEL ORTHO-SUBSTITUENT EFFECT ON FORMATION OF VINYL CATIONS IN THE PHOTOLYSIS OF VINYL BROMIDES

Introduction of a substituent into ortho-position of β-aryl group in a vinyl bromide resulted in the preferential formation of a vinyl cation in the photolysis.It is considered that the steric repulsion of β-aryl groups makes a convenient conformation for an electron transfer from the aromatic ring to the halogen atom in the radical pair.

η2-BENZOPHENOZIRCONOCEN, EIN MODELL FUER DAS REACTIONSVERHALTEN EINES METALLAOXIRANS?

Thermolysis of η2-benzoyl(phenyl)zirconocene yields the η2-benzophenonzirconocene complex 2, isolated as a dimer. 2 exhibits an ambivalent reactivity pattern.The formation of five-membered metallacycles from 2 and olefinic hydrocarbons possibly proceeds analogous to reactions of "normal" metal-olefin ?-complexes.However, both reactions with the electron-deficient olefins dimethylfumarate and -maleate and the behavior towards electrophilic and protic reagents as well as aromatic hydrocarbons might be interpreted in terms of a metallaoxirane-character of 2.