4359-49-3

Basic information

• Product Name: 2-ethyl-2-phenyl-1,3-dioxolane
• Synonyms: 2-ethyl-2-phenyl-1,3-dioxolane
• CAS NO: 4359-49-3
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.2277
• Mol File: 4359-49-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 254.5°Cat760mmHg
• Flash Point: 110.6°C
• Appearance: /
• Density: 1.042g/cm³
• Vapor Pressure: 0.0275mmHg at 25°C
• Refractive Index: 1.505
• CAS DataBase Reference: 2-ethyl-2-phenyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ethyl-2-phenyl-1,3-dioxolane(4359-49-3)
• EPA Substance Registry System: 2-ethyl-2-phenyl-1,3-dioxolane(4359-49-3)

Safety Data

• Hazardous Substances Data: 4359-49-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H14O2/c1-2-11(12-8-9-13-11)10-6-4-3-5-7-10/h3-7H,2,8-9H2,1H3

Upstream product

• 107-21-1 ethylene glycol 
• 93-55-0 1-phenyl-propan-1-one 
• 29568-65-8 α-Bromopropiophenone cyclic ethylene acetal 
• 110-82-7 cyclohexane 
• 673-32-5 1-Phenylprop-1-yne 

Downstream Products

• 93-54-9 1-Phenyl-1-propanol 
• 91968-37-5 2-(1'-phenylpropoxy)ethanol 
• 23246-00-6 propiophenone-((E)-2,4-dinitro-phenylhydrazone) 
• 29568-65-8 α-Bromopropiophenone cyclic ethylene acetal 
• 93-55-0 1-phenyl-propan-1-one 
• 33662-99-6 2-chloroethyl 2-phenylpropionate 

Relevant articles and documents

Experimental and Theoretical Study of the Effectiveness and Stability of Gold(I) Catalysts Used in the Synthesis of Cyclic Acetals

Different [AuL]+ fragments (L = tertiary phosphines, ylides, or NHC carbene) have been tested under mild conditions as suitable catalysts for the transformation of terminal or internal alkynes into the corresponding cyclic acetals upon reaction

Synthesis and reactions of [(((η6)-2-acylaryl)-C,O) tetracarbonylmanganese]-tricarbonylchromium complexes: Enhancement of diastereoselection during cyclopentaannulation

Cyclomanganation reactions of [(η6)-acylaryl]tricarbonylchromium complexes have been investigated. Three novel heterobimetallic complexes have been synthesised in moderate to good yield, with one being characterised by X-ray crystallography. Several modes of activating these bimetallic complexes towards coupling reactions with substituted alkenes and alkynes were investigated, including oxidative decarbonylation at room temperature, and thermal promotion. The stereochemistry of one of the cyclopentaannulated adducts has been established by X-ray crystallography. Thermal displacement of one of the CO ligands of the bimetallic complex 27 in the presence of PPh3 afforded a single adduct, the structure of which was established by X-ray crystallography. The chemistry of this novel bimetallic system was investigated.

Modification of the Photochemical Reactivity of Cyclic Ethylene Acetal of α-Bromopropiophenone by Adsorption within Zeolites. A Combined Contribution of Lewis Acidity and Cage Effect in the Formation of a 2-Phenylpropanoate via 1,2-Phenyl Shift

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