91968-37-5

Basic information

• Product Name: Ethanol, 2-(1-phenylpropoxy)-
• CAS NO: 91968-37-5
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol File: 91968-37-5.mol

Chemical Properties

• Boiling Point: 119-120 °C(Press: 6 Torr)
• Density: 1.0106 g/cm3
• CAS DataBase Reference: Ethanol, 2-(1-phenylpropoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol, 2-(1-phenylpropoxy)-(91968-37-5)
• EPA Substance Registry System: Ethanol, 2-(1-phenylpropoxy)-(91968-37-5)

Safety Data

• Hazardous Substances Data: 91968-37-5(Hazardous Substances Data)

Upstream product

• 107-21-1 ethylene glycol 
• 934-11-2 (1-Chloro-propyl)-benzene 
• 936-51-6 2-phenyl-1,3-dioxolane 
• 97-93-8 triethylaluminum 
• 4359-49-3 2-ethyl-2-phenyl-1,3-dioxolane 
• 122405-06-5 ethyl-(β-hexyl)alumocyclopentane 
• 93-54-9 1-Phenyl-1-propanol 
• 91968-53-5 1-phenylpropyl methoxymethyl ether 
• 96-10-6 diethylaluminium chloride 

Relevant articles and documents

Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

Abstract: The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mix

Reaction of 2-mono- and 2,2-disubstituted 1,3-dioxolanes with 1-ethyl-3-hexylaluminacyclopentane

Reaction of 2-mono- and 2,2-disubstituted 1,3-dioxolanes with 1-ethyl-3-hexylaluminacyclopentane involves cleavage of the Al-C bond of the metal cycle and formation, after hydrolysis, ethylene glycol monoethers. Catalytic amounts of ZrCl4 or Ni(acac)

Reactions of trialkylalanes with cyclic acetals and orthoformates in CH2Cl2 and ClCH2CH2Cl as solvents

Under mild conditions, trialkylalanes (Et3Al and Bu i3Al) in chlorine-containing solvents (CH 2Cl2 or ClCH2CH2Cl) react with cyclic acetals and orthoformates to form glycol monoethers and dialkylacetals, respectively, in high yields. The 1H NMR spectroscopic data demonstrate that CH2Cl2 or ClCH2CH 2Cl interacts with Bui3Al.

TRANSFORMATION OF 1,3-DIOXACYCLOALKANES BY THE ACTION OF DIETHYLALUMINUM HYDRIDE AND TRIETHYLALUMINUM.

There are reports on the reduction of ethylene glycol acetals and ketals by aluminum hydrides to the corresponding monoethers. Considering that these compounds find wide application as solvents, plasticizers, and perfume ingredients, it was of interest to study the possibility of a selective hydrogenation of different 1,3-dioxacycloalkanes by industrial grade mixtures of diethylaluminum hydride and triethylaluminum. According to the data obtained for the reactions with cyclic acetals, triethylaluminum is 1. 5-2 times more active than diethylaluminum hydride. The activities of the five-membered ring acetals and ketals in the reduction and alkylation processes are similar; 2-phenyl-1, 3-dioxolane has the highest reactivity. Thus, 2-mono- and 2,2-disubstituted 1,3-dioxacyclanes form monoethers of the correepsponding diols by the action of diethylaluminum hydride and triethylauminum. In the case of triethylaluminum, ethylation of the carbon atom adjacent to the two oxygen atoms takes place.