437655-37-3Relevant academic research and scientific papers
Enantioselective cyanosilylation of ketones catalyzed by a chiral oxazaborolidinium ion
Do, Hyun Ryu,Corey
, p. 5384 - 5387 (2005)
The chiral oxazaborolidinium salt 1 (X = TfO) is an excellent catalyst for the cyanosilylation of methyl ketones promoted by trimethylsilyl cyanide and diphenylmethyl phosphine oxide as co-reactants (to generate Ph 2MePOTMS(N=C:) as a reactive
Effective activation of the chiral salen/Ti(OiPr)4 catalyst with achiral phenolic N-oxides as additives in the enantioselective cyanosilylation of ketones
He, Bin,Chen, Fu-Xue,Li, Yan,Feng, Xiaoming,Zhang, Guolin
, p. 4657 - 4666 (2007/10/03)
The activation of chiral titanium(IV) complexes with phenolic N-oxides additives has been found to provide an alternative strategy for the asymmetric cyanosilylation of ketones. By using 10 mol % of chiral salen-titanium(IV) complex in combination with 1
