4389-39-3

Usage

InChI:InChI=1/C16H16O2/c1-11-7-3-5-9-13(11)15(17)16(18)14-10-6-4-8-12(14)2/h3-10,15,17H,1-2H3

Upstream product

• 100-52-7 benzaldehyde 
• 529-20-4 2-methylphenyl aldehyde 
• 64158-25-4 2,2'-dimethylhydrobenzoin 

Downstream Products

• 27962-48-7 2-hydroxy-1,2-di-o-tolyl-pent-4-en-1-one 
• 64158-25-4 meso-1,2-bis(2-methylphenyl)ethane-1,2-diol 
• 34737-70-7 threo-1,2-bis(2-methylphenyl)ethane-1,2-diol 
• 118-90-1 ortho-methylbenzoic acid 
• 1309965-12-5 (S)-2-hydroxy-1,2-di-o-tolylethan-1-one 
• 2048-07-9 1,2-bis(2-methylphenyl)-1,2-ethanedione 
• 34712-68-0 meso-2,2'-Dimethylhydrobenzoin-sulfit 
• 64158-25-4 2,2'-dimethylhydrobenzoin 
• 916525-65-0 [1,2-bis(2-methylphenyl)-2-(2-methylpropoxy)ethoxy]-7,8,8-trimethyloctahydro-4,7-methanobenzo[b]furan 
• 916525-60-5 1,2-bis(2-methylphenyl)-2-[(7,8,8-trimethyloctahydro-4,7-methanobenzo[b]furan-2-yl)oxy]ethanol 
• 916525-77-4 oxophenylacetic acid (1R,2S)-1,2-bis(2-methylphenyl)-2-(2-methylpropoxy)ethyl ester 
• 916525-82-1 hydroxy(phenyl)acetic acid (1R,2S)-1,2-bis(2-methylphenyl)-2-(2-methylpropoxy)ethyl ester 
• 916525-72-9 (1R,2S)-1,2-bis(2-methylphenyl)-2-(2-methylpropoxy)ethanol 
• 900809-57-6 4-hydroxy-3,4-di(o-tolyl)cyclopent-2-enone 

Relevant academic research and scientific papers

NaBrO3/bmim[HSO4]: a versatile system for the selective oxidation of 1,2-diols, α-hydroxyketones, and alcohols

Abstract: Sodium bromate with bmim[HSO4] has been found to be an excellent oxidizing agent in aqueous medium. NaBrO3:bmim[HSO4] oxidized 1,2-diols, α-hydroxyketones, and alcohols to the corresponding carbonyl compounds in excellent yields. This method offers advantages such as low cost reagents, aqueous reaction conditions, moderate temperatures and short reaction times and hence environmentally benign reaction. Moreover, the ionic liquid bmim[HSO4] could be recycled for at least three times without loss of significant activity. Graphical abstract: [Figure not available: see fulltext.]

A family of thiazolium salt derived N-heterocyclic carbenes (NHCs) for organocatalysis: Synthesis, investigation and application in cross-benzoin condensation

A family of thiazolium salt derived N-heterocyclic carbenes (NHCs) bearing sterically demanding aryl substituents on the nitrogen and with varying backbone substitution patterns have been synthesized. Investigation of the catalytic activity of these NHCs in a number of benzoin-type coupling reactions revealed markedly different levels of reactivity and selectivity. To elucidate the underlying factors leading to differences in reactivity, a study of the electronic and steric properties of these NHC catalysts was conducted. By using the best catalyst in this study, the intermolecular cross-benzoin condensation reaction was explored in more detail.