439867-23-9

Basic information

• Product Name: bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)
• CAS NO: 439867-23-9
• Molecular Weight: 892.735
• Mol File: 439867-23-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)(439867-23-9)
• EPA Substance Registry System: bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)(439867-23-9)

Safety Data

• Hazardous Substances Data: 439867-23-9(Hazardous Substances Data)

Upstream product

• 43067-26-1 (cyclohexylisocyanide)gold(I) chloride 
• 17534-15-5 Benzene-1,2-dithiol 
• 75-09-2 dichloromethane 

Relevant articles and documents

Preparation and crystal structure of bis(isocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurates(III)

The reaction of (isocyanide)gold(I) chlorides [(RNC)AuCl, R = tBu, cHex] with phenylene-1,2-dithiol and sodium methoxide (molar ratio 2:1:2) in methanol / dichloromethane leads to the formation of deep green mixed-valent salts [(RNC)2Au]+[Au(S2C6H 4)2]- in ca. 35% yield. As determined by single crystal X-ray diffraction methods, the two compounds have entirely different supramolecular structures. For R = tBu stacked planar anions and rod-like cations form alternating layers, while for R = cHex alternating cations and anions are arranged in chains with long S- -Au contacts [3.422 ?].