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4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI, also known as 1-(4-Sulfobutyl)-3-butylimidazolium Trifluoromethanesulfonate, is an ionic liquid that plays a crucial role in the synthesis of various organic compounds. It is characterized by its unique chemical structure, which consists of a butylimidazolium cation and a butanesulfonate anion. This ionic liquid exhibits excellent solvation properties and has been widely used as a catalyst in various chemical reactions.

439937-63-0

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439937-63-0 Usage

Uses

Used in Chemical Synthesis:
4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI is used as a catalyst in the preparation of Me Glycolate through an ionic liquid-catalyzed three-component reaction of Trioxymethylene, water, and CO, followed by esterification with MeOH. This process demonstrates the versatility and efficiency of 4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI in facilitating the synthesis of valuable organic compounds.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI is used as a catalyst for the synthesis of various active pharmaceutical ingredients (APIs). Its ability to promote efficient and selective reactions makes it a valuable tool in the development of new drugs and the improvement of existing ones.
Used in Environmental Applications:
4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI is also used in environmental applications, such as the treatment of wastewater and the removal of pollutants. Its unique properties allow it to effectively break down or capture harmful substances, contributing to a cleaner and more sustainable environment.
Used in Energy Storage and Conversion:
In the field of energy storage and conversion, 4-(3-BUTYL-1-IMIDAZOLIO)-1-BUTANESULFONI is used in the development of advanced materials for batteries, fuel cells, and other energy-related technologies. Its ability to improve the performance and stability of these materials makes it a promising candidate for future energy solutions.

Check Digit Verification of cas no

The CAS Registry Mumber 439937-63-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,3,9,9,3 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 439937-63:
(8*4)+(7*3)+(6*9)+(5*9)+(4*3)+(3*7)+(2*6)+(1*3)=200
200 % 10 = 0
So 439937-63-0 is a valid CAS Registry Number.
InChI:InChI=1/C11H20N2O3S.CHF3O3S/c1-2-3-6-12-8-9-13(11-12)7-4-5-10-17(14,15)16;2-1(3,4)8(5,6)7/h8-9,11H,2-7,10H2,1H3;(H,5,6,7)

439937-63-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(3-butylimidazol-1-ium-1-yl)butane-1-sulfonic acid,trifluoromethanesulfonate

1.2 Other means of identification

Product number -
Other names 1-Butyl-3-(4-sulfobutyl)imidazolium triflate,trifluoromethanesulfonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:439937-63-0 SDS

439937-63-0Downstream Products

439937-63-0Relevant academic research and scientific papers

Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts

Cole, Amanda C.,Jensen, Jessica L.,Ntai, Ioanna,Tran, Kim Loan T.,Weaver, Kristin J.,Forbes, David C.,Davis Jr., James H.

, p. 5962 - 5963 (2002)

The reaction of triphenylphosphine or N-butylimidazole with cyclic sultones gives zwitterions that are subsequently converted into ionic liquids by reaction with trifluoromethane sulfonic acid or p-toluenesulfonic acid. The resulting ionic liquids have cations to which are tethered alkane sulfonic acid groups. These Bronsted acidic ionic liquids are useful solvent/catalysts for several organic reactions, including Fischer esterification, alcohol dehydrodimerization and the pinacol rearrangement. The new ionic liquids combine the low volatility and ease of separation from product normally associated with solid acid catalysts, with the higher activity and yields normally found using conventional liquid acids. Copyright

Chemical Analysis of Ionic Liquids Using Photoelectron Spectroscopy

Seo, Sungyong,Park, Juyun,Kang, Yong-Cheol

, p. 355 - 360 (2016/03/15)

The feasibility of utilizing X-ray photoelectron spectroscopy (XPS) to analyze roomerature ionic liquids (RTILs) was investigated in this study. Conventionally, the chemical structure of organic compounds is identified by nuclear magnetic resonance (NMR) spectroscopy. The properties of RTILs, especially their low vapor pressure, make it possible to analyze RTILs by using XPS. The usefulness of XPS on RTILs was confirmed by commercial RTILs. All atoms in RTILs were detected in survey XPS spectra, and the calculated atomic percentages matched well with theoretical values. After the verification of commercial RTILs by XPS, we synthesized three RTILs and investigated them with XPS. The atomic ratio and chemical environment of carbon in RTILs were verified by XPS. By adapting XPS to the investigation of RTILs, carbon atoms in different chemical environments were distinguishable by the binding energy shift, and the atomic ratio of the constituent atoms was identifiable after peak deconvolution. In addition, inorganic constituents were detected by XPS unlike in the case of NMR spectroscopy.

Oligomerisation of isobutene with silica supported ionic liquid catalysts

Feher, Csaba,Krivan, Eszter,Hancsok, Jen,Skoda-Foeldes, Rita

, p. 403 - 409 (2012/04/10)

Bronsted acidic ionic liquids, supported on silica gel, have been used effectively in oligomerisation of isobutene. The supported catalysts could be used several times without loss of activity or change in selectivity. The ratio of the products could be influenced by the proper choice of the ionic liquid component of the catalyst and the reaction temperature.

Synthesis of 1-octanol and 1,1-dioctyl ether from biomass-derived platform chemicals

Julis, Jennifer,Leitner, Walter

, p. 8615 - 8619 (2012/09/21)

The happy medium: A new catalytic pathway for the synthesis of the linear primary C8?alcohol products 1-octanol and dioctyl ether from furfural and acetone has been developed using retrosynthetic analysis. This opens a general strategy for the synthesis of medium-chain-length alcohols from carbohydrate feedstock.

Broensted acidic ionic liquids as efficient and recyclable catalysts for the carbonylation of formaldehyde

Song, Heyuan,Li, Zhen,Chen, Jing,Xia, Chungu

experimental part, p. 81 - 86 (2012/04/10)

Methyl glycolate (MG), as a precursor to ethylene glycol (EG), was synthesized by an efficient and eco-friendly procedure of one-pot, two-step, sequential reaction, including carbonylation and esterification from HCHO with Broensted acidic ionic liquids (BAILs) as catalysts. MG was obtained in high yield under mild conditions. In addition, the catalyst could be recycled eight times after separating the unreacted materials and products from the reaction system by distillation under vacuum and no significant decrease in catalytic activity was observed.

Intramolecular hydroalkoxylation in Bronsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Jeong, Yunkyung,Kim, Do-Young,Choi, Yunsil,Ryu, Jae-Sang

supporting information; experimental part, p. 374 - 378 (2011/02/28)

The SO3H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Bronsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

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