4403-13-8Relevant academic research and scientific papers
REACTION OF HEXAMETHYLDISILOXANE WITH 2-ETHOXY-1,3-DIOXOLANE
Zhurkina, I. P.,Nedogrei, E. P.,Musavirov, R. S.,Kondrat'eva, I. A.,Rakhmankulov, D. L.
, p. 1338 - 1342 (2007/10/02)
The reaction of hexamethyldisiloxane with 2-ethoxy-1,3-dioxolane is described.It is shown that cleavage of the endo- and exocyclic carbon-oxygen bonds of the ortho ester occurs under mild condition (16 - 20 deg C) in the presence of acidic catalysts with
EFFECTS OF VARYING THE MEDIA FOR BASE CLEAVAGE OF SOME BENZYL-SILICON AND-TIN COMPOUNDS IN ALCOHOLS
Eaborn, Colin,Mahmoud, Foad M.S.
, p. 49 - 58 (2007/10/02)
The effects on the rates of cleavage of 3-ClC6H4CH2MMe3 and 3,5-Cl2C6H3CH2MMe3 compounds with M = Si and Sn have been examined for (a) various concentrations of NaOMe-MeOH; (b) various concentrations of H2O in NaOH-H2O-MeOH; and (c) variation of R from Me to Et, i-Pr and t-Bu for metal alkoxide-ROH mixtures.Rates have also been measured for cleavages in NaOCH2CF3HOCH2CF3-Me2SO.In all cases there are differences in behaviour between the silicon and tin compounds which are consistent with the postulated difference in the mechanisms of their reactions.
