4403-14-9Relevant articles and documents
Titanocene dichloride complexes bonded to carbosilane dendrimers via a spacer of variable length - Molecular dynamics calculations and catalysis of allylic coupling reactions Metallodendrimers Special Issue
Stra?ák, Tomá?,Jaroschik, Florian,Maly, Marek,?ermák, Jan,Sykora, Jan,Fajgar, Radek,Karban, Jind?ich,Harakat, Dominique
, p. 137 - 146 (2014)
Carbosilane metallodendrimers of the first generation Si{CH 2CH2CH2SiMe2CH2CH 2SiMe2(CH2)nC5H 4TiCl2C5H5/s
Luminescent tungsten(vi) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions
Chan, Kaai-Tung,Che, Chi-Ming,Du, Lili,Liu, Yungen,Phillips, David Lee,To, Wai-Pong,Tong, Glenna So Ming,Wu, Liang-Liang,Yu, Daohong
, p. 6370 - 6382 (2020/07/15)
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
Manganese- or iron-catalyzed homocoupling of grignard reagents using atmospheric oxygen as an oxidant
Cahiez, Gerard,Moyeux, Alban,Buendia, Julien,Duplais, Christophe
, p. 13788 - 13789 (2008/04/11)
Atmospheric oxygen was used for the first time as an oxidant in metal-catalyzed homocoupling of Grignard reagents. These manganese- or iron-catalyzed reactions are efficient, cheap, and eco-friendly. They are applicable to the large-scale synthesis of symmetrical conjugated compounds. Copyright