4403-20-7Relevant articles and documents
In/InCl3-mediated cross-coupling reactions of methyl vinyl ketone with benzaldehyde in aqueous media
Kang, Soyeon,Jang, Taeg-Su,Keum, Gyochang,Kang, Soon Bang,Han, So-Yeop,Kim, Youseung
, p. 3615 - 3617 (2000)
(matrix presented) Various β,γ-unsaturated ketones were successfully prepared by cross-coupling reactions of methyl vinyl ketone (MVK) with benzaldehydes mediated by In/InCl3 in aqueous media.
First pinacol coupling in emulsified water: Key role of surfactant and impact of alternative activation technologies
Billamboz, Muriel,Len, Christophe
, p. 1664 - 1675 (2015/06/02)
For the first time, the influence of surfactants on the radical pinacol coupling reaction is investigated. The rate and selectivity of this reductive C-C coupling are compared under three different activation technologies: thermal activation, microwave irradiation, and sonication. The use of IgepalCO520, a neutral surfactant, led to the successful conversion of aromatic or α,β-unsaturated aliphatic carbonyl compounds in moderate to excellent yield (55-90 %). An insight on the potential mechanism involved in the reaction is also proposed, based on microscopic observations and particle size measurement.
Mg/Triethylammonium formate: A useful system for reductive dimerization of araldehydes into pinacols; Nitroarenes into azoarenes and azoarenes into hydrazoarenes
Pamar, M. Geeta,Govender,Muthusamy,Krause, Ruiw M.,Nanjundaswamy
, p. 969 - 974 (2014/03/21)
Studies are reported which describes the effectiveness of triethylammonium formate in the presence of magnesium for the efficient intermolecular pinacol coupling using MeOH as solvent, Various aromatic carbonyls underwent smooth reductive coupling to give the corresponding I ,2-diols. A series of azo compounds were obtained by the reductive coupling of nitroaromatics while azo compounds were reduced to the corresponding hydrazoarenes by this system. There was no adverse effect on the other reducible and hydrogenolysable groups such as ether linkage, hydroxy and halogens. The reactions are clean, high yielding and inexpensive. All the reactions proceeded smoothly at ambient temperature.