37973-54-9

Basic information

• Product Name: 2-Propene-1,1-diol, 3-phenyl-, diacetate, (2E)-
• CAS NO: 37973-54-9
• Molecular Formula: C13H14O4
• Molecular Weight: 234.252
• Mol File: 37973-54-9.mol
• Article Data: 75

Chemical Properties

• CAS DataBase Reference: 2-Propene-1,1-diol, 3-phenyl-, diacetate, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propene-1,1-diol, 3-phenyl-, diacetate, (2E)-(37973-54-9)
• EPA Substance Registry System: 2-Propene-1,1-diol, 3-phenyl-, diacetate, (2E)-(37973-54-9)

Safety Data

• Hazardous Substances Data: 37973-54-9(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 108-24-7 acetic anhydride 
• 104-55-2 3-phenyl-propenal 
• 7664-93-9 sulfuric acid 
• 300-57-2 allylbenzene 
• 64-19-7 acetic acid 
• 103-54-8 cinnamyl acetate 

Downstream Products

• 137936-56-2 6-(2-acetoxy-4-phenyl-trans-3-butenyl)-6-methylfulvene 
• 118171-44-1 2,2,2-trichloro-1-styrylethyl acetate 
• 104-55-2 3-phenyl-propenal 
• 122-97-4 3-Phenyl-1-propanol 
• 104-54-1 3-Phenylpropenol 
• 4403-20-7 1,6-diphenyl-hexa-1,5-diene-3,4-diol 
• 64-19-7 acetic acid 
• 1216-15-5 cinnamaldehyde phenylhydrazone 
• 26958-41-8 cinnamyl-1,3-dithiane 
• 5616-58-0 2-styryl-1,3-dithiolane 
• 849-01-4 1,3,3-triphenylprop-2-en-1-one 
• 5424-75-9 prop-2-ene-1,1,3-triyltribenzene 
• 33018-48-3 3-phenyl-3H-benzo[f]chromene 
• 95745-36-1 3,3'-bisindolyl-1-(2-phenylethylene)methane 

Relevant articles and documents

The studies on chemoselective promiscuous activity of hydrolases on acylals transformations

Chemoselective, mild and convenient protocol for the hydrolysis of the synthetically relevant acylals via promiscuous enzyme-catalyzed hydrolysis has been developed. It has been shown that promiscuous activity of the used hydrolases dominates their native activity related with carboxylic esters hydrolysis. The main advantage of the present methodology is that it can be conducted under neutral conditions at room temperature. Moreover, complete deprotection of acylals takes place within 10–20 min. Developed protocol can be used with compounds having a variety of hydrolytic labile groups since the cleavage is proceeded under neutral conditions and occurs exclusively on acylal moiety. Further this protocol was extended by the tandem Passerini multicomponent reaction leading to the α-acetoxy amides using acylals as the surrogates of the carbonyl components to P-MCR.

SiO2@FeSO4 nano composite as nanocatalyst for the green synthesis 1,1-diacetates from aldehydes under solvent-free conditions

Aldehydes compounds selective converted to 1,1-diacetates as protective reagent with SiO2@FeSO4 nano composite as effective nano catalyst at room temperature under solvent-free condition and acetic anhydride (Ac2O) as acet

Synthesis of 1,1-diacetates catalyzed by cellulose sulfonic acid from aldehydes and acetic anhydride

1,1-Diacetates have been synthesized in good to excellent yields via a reaction of corresponding aldehydes and acetic anhydride in the presence of cellulose sulfonic acid as a heterogeneous catalyst at room temperature. The protection of aldehydes generated an anhydrodimer as single product under similar reaction conditions. The catalysis is equally applicable for the deprotection of acylal in acetonitrile.