4409-98-7

Usage

Uses

Used in Chemical Industry:
DI-POTASSIUM PHTHALATE is used as a chemical compound for the preparation of brucite-like Ca2+/Al3+ layered double hydroxide (LDH), Ca2Al(OH)6·NO3·2H2O. This application is significant because it contributes to the development of new materials with specific properties and potential uses in various fields.

InChI:InChI=1/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);

Upstream product

• 85-44-9 phthalic anhydride 
• 5336-97-0 N–nitrophthalimide 
• 88-99-3 benzene-1,2-dicarboxylic acid 

Downstream Products

• 17899-04-6 Phthalsaeure-bis-trimethylsilylmethylester 
• 883-44-3 N-(3-hydroxypropyl)phthalimide 
• 633303-94-3 2-{2-[3-(Phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridine-1-yl]ethyl}-1H-isoindole-1,3(2H)-dione 
• 46279-13-4 copper(II) phthalate monohydrate 
• 10027-30-2 copper(II) phthalate 
• 100-21-0 terephthalic acid 

Relevant academic research and scientific papers

METHODS FOR PRODUCTION OF TEREPHTHALIC ACID FROM ETHYLENE OXIDE

The present invention provides methods for the production of terephthalic acid and derivatives thereof using ethylene oxide, carbon monoxide and furan as feedstocks. The process is characterized by high yields and high carbon efficiency. The process can utilize 100% biobased feedstocks (EO via ethanol, CO via biomass gasification, and furan via known processes from cellulosic feedstocks).

Metal-organic fireworks: MOFs as integrated structural scaffolds for pyrotechnic materials

A new approach to formulating pyrotechnic materials is presented whereby constituent ingredients are bound together in a solid-state lattice. This reduces the batch inconsistencies arising from the traditional approach of combining powders by ensuring the key ingredients are 'mixed' in appropriate quantities and are in intimate contact. Further benefits of these types of material are increased safety levels as well as simpler logistics, storage and manufacture. A systematic series of new frameworks comprising fuel and oxidiser agents (group 1 and 2 metal nodes & terephthalic acid derivatives as linkers) has been synthesised and structurally characterised. These new materials have been assessed for pyrotechnic effect by calorimetry and burn tests. Results indicate that these materials exhibit the desired pyrotechnic material properties and the effect can be correlated to the dimensionality of the structure. A new approach to formulating pyrotechnic materials is proposed whereby constituent ingredients are bound together in a solid-state lattice. A series of Metal-organic framework frameworks comprising fuel and oxidiser agents exhibits the desired properties of a pyrotechnic material and this effect is correlated to the dimensionality of the structure.

Noncovalent catch and release of carboxylates in water

Association constants of a bis-(acetylguanidinium)ferrocene dication to various (di)carboxylates were determined through UV-vis titrations. Association constant values greater than 104 M-1 were determined for both phthalate and maleate carboxylates to the bis-(acetylguanidinium)ferrocene salt in pure water. Density functional theory computations of the binding enthalpy of the rigid carboxylates for these complexes agree well with the experimentally determined association constants. Catch and release competitive binding experiments were done by NMR for the cation-carboxylate ion-pair complexes with cucurbit[7]uril, and they show dissociation of the ion-pair complex upon addition of cucurbit[7]uril and release of the free (di)carboxylate.