442202-05-3

Basic information

• Product Name: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate
• Synonyms: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate
• CAS NO: 442202-05-3
• Molecular Weight: 467.637
• Mol File: 442202-05-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate(442202-05-3)
• EPA Substance Registry System: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate(442202-05-3)

Safety Data

• Hazardous Substances Data: 442202-05-3(Hazardous Substances Data)

Upstream product

• 209257-75-0 (S)-6-((tert-butyldiphenylsilyloxy)methyl)piperidin-2-one 
• 442202-20-2 methyl (6S)-(-)-2-(tert-butyldiphenylsilyloxymethyl)-6-oxopiperidine-1-carboxylate 
• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 442202-21-3 methyl (6S)-(-)-2-(tert-butyldiphenylsilyloxymethyl)-6-trifluoromethanesulfonyloxy-3,4-dihydro-2H-pyridine-1-carboxylate 

Downstream Products

• 442202-22-4 dimethyl (2R,3S,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-3-vinyl-piperidine-1,2-dicarboxylate 
• 619266-91-0 dimethyl (2R,3R,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-3-methylpiperidine-1,2-dicarboxylate 
• 442202-09-7 dimethyl (2S,3R,5R,6S)-(-)-5-ethyl-6-propyl-3-vinylpiperidine-1,2-dicarboxylate 
• 442202-23-5 methyl (2S,3S,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-2-propenyl-3-vinylpiperidine-1-carboxylate 
• 442202-06-4 methyl (2R,3S,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-2-hydroxymethyl-3-vinylpiperidine-1-carboxylate 
• 619267-06-0 methyl (8R,9R)-(-)-8-methyl-3-oxo-5-phenylsulfanylhexahydrooxazolo[3,4-a]pyridine-5-carboxylate 
• 619266-92-1 (5S,8R,9R)-(-)-5-(tert-butyldiphenylsilyloxymethyl)-8-methylhexahydrooxazolo[3,4-a]pyridin-3-one 
• 619267-04-8 methyl (2R,3R,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-2-hydroxymethyl-3-methylpiperidine-1-carboxylate 
• 1026511-23-8 (2R,3S,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2-ethoxycarbonyloxycarbonyl-3-vinyl-piperidine-1-carboxylic acid methyl ester 
• 460054-05-1 methyl (2S,3S,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-2-{(methoxy-methylcarbamoyl)methyl}-3-vinylpiperidine-1-carboxylate 
• 460054-20-0 methyl (2S,4aR,5S,8aS)-(-)-2-(tert-butyldiphenylsilyloxymethyl)-5-methyl-7-oxo-octahydroquinoline-1-carboxylate 
• 460054-25-5 methyl (2S,4aS,8aS)-(-)-2-(tert-butyldiphenylsilyloxymethyl)-5-methyl-7-oxo-3,4,4a,7,8,8a-hexahydro-2H-quinoline-1-carboxylate 
• 460054-07-3 methyl (2S,3S,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-2-(2-oxopropyl)-3-vinylpiperidine-1-carboxylate 
• 460054-03-9 methyl (2S,3S,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-2-{(methoxy-carbonyl)methyl}-3-vinylpiperidine-1-carboxylate 

Relevant articles and documents

Stereodivergent synthesis of the 2,3,5,6-tetrasubstituted piperidine ring system: An application to the synthesis of alkaloids

Stereodivergent synthesis of the 2,3,5,6-tetrasubstituted piperidine ring system has been achieved by sequential stereocontrolled Michael-type conjugate addition reaction of appropriate enaminoesters. This methodology has been applied to the total synthes