443306-62-5Relevant articles and documents
Regio- and Stereoselective Homolytic Hydrostannylation of Propargyl Alcohols and Ethers with Dibutylchlorostannane
Miura, Katsukiyo,Wang, Di,Matsumoto, Yukihiro,Fujisawa, Naoki,Hosomi, Akira
, p. 8730 - 8732 (2003)
The Et3B-initiated reaction of γ-unsubstituted propargyl alcohols with dibutylchlorostannane (Bu2SnClH) at low temperature gave (Z)-vinylstannanes with high regio- and stereoselectivity. The corresponding alkyl propargyl ethers also
A new ruthenium-catalyzed hydrogen-transfer reaction: Transformation of 3-benzyl but-1-ynyl ethers into 1,3-dienes and benzaldehyde
Yeh, Kuo-Liang,Liu, Bo,Lo, Ching-Yu,Huang, Heh-Lung,Liu, Rai-Shung
, p. 6510 - 6511 (2007/10/03)
(Chemical Equqtion Presentation) We report a ruthenium-catalyzed reaction for various 3-benzyl but-1-ynyl ethers with suitable functionalities. Treatment of these substrates with TpRu(PPh3)(CH3CN)2PF6 (8.0 mol %