4436-85-5Relevant academic research and scientific papers
Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2
van Gemmeren, Manuel,B?rjesson, Marino,Tortajada, Andreu,Sun, Shang-Zheng,Okura, Keisho,Martin, Ruben
supporting information, p. 6558 - 6562 (2017/05/29)
A switchable site-selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C?OH cleavage and as a C1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can be modulated by the type of ligand employed.
Ligand-controlled regiodivergent Ni-catalyzed reductive carboxylation of allyl esters with CO2
Moragas, Toni,Cornella, Josep,Martin, Ruben
, p. 17702 - 17705 (2015/02/19)
A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.
