443752-40-7

Upstream product

• 443752-41-8 (E)-(2R,6S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-(4-methoxy-benzyloxy)-2,4,6-trimethyl-hept-4-en-3-one 
• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 824-94-2 p-methoxybenzyl chloride 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 160238-46-0 (2R)-3-(4-methoxybenzyloxy)-2-methyl-1-propanal 
• 212051-35-9 (R)-methyl 3-((4-methoxybenzyl)oxy)-2-methylpropanoate 
• 443752-42-9 [4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-2-oxo-butyl]-phosphonic acid diethyl ester 

Downstream Products

• 443752-44-1 (2R,3R,5R,6R)-1-(tert-Butyl-diphenyl-silanyloxy)-7-(4-methoxy-benzyloxy)-2,6-dimethyl-4-methylene-heptane-3,5-diol 
• 443752-46-3 (3R,4R)-5-(tert-Butyl-diphenyl-silanyloxy)-2-[(4R,5R)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-4-methyl-pent-1-en-3-ol 
• 443752-39-4 (1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-{(2S,3S)-3-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2-methyl-oxiranyl}-2-methyl-propan-1-ol 
• 443752-43-0 (1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-{(2R,3R)-3-[(R)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-2-methyl-oxiranyl}-2-methyl-propan-1-ol 

Relevant academic research and scientific papers

Studies directed toward the synthesis of the C15-C21 fragment of (-)-discodermolide

A novel method developed by us recently for the synthesis of chiral 2-methyl-1,3-diols by radical-mediated diastereoselective opening of trisubstituted epoxy alcohols at the more substituted carbon serves as the key step in our studies directed toward the