443791-03-5

Basic information

• Product Name: Acetamide, 2-diazo-N-(trans-2-phenyl-1,3-dioxan-5-yl)-N-(phenylmethyl)-
• CAS NO: 443791-03-5
• Molecular Formula: C19H19N3O3
• Molecular Weight: 337.378
• Mol File: 443791-03-5.mol

Chemical Properties

• CAS DataBase Reference: Acetamide, 2-diazo-N-(trans-2-phenyl-1,3-dioxan-5-yl)-N-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, 2-diazo-N-(trans-2-phenyl-1,3-dioxan-5-yl)-N-(phenylmethyl)-(443791-03-5)
• EPA Substance Registry System: Acetamide, 2-diazo-N-(trans-2-phenyl-1,3-dioxan-5-yl)-N-(phenylmethyl)-(443791-03-5)

Safety Data

• Hazardous Substances Data: 443791-03-5(Hazardous Substances Data)

Upstream product

• 674-82-8 4-methyleneoxetan-2-one 
• 443791-02-4 trans-5-(N-benzylamino)-2-phenyl-1,3-dioxane 
• 100-46-9 benzylamine 
• 52941-82-9 2-phenyl-1,3-dioxan-5-one 

Downstream Products

• 121686-86-0 cis-N-benzyl-4-hydroxy-5-(hydroxymethyl)pyrrolidin-2-one 

Relevant articles and documents

Highly Selective Synthesis of a 2-Deoxyxylonolactam via Enantioselective Carbon-Hydrogen Insertion Reactions Using Chiral Dirhodium(II) Carboxamidates

N-Benzyl-2-deoxyxylonolactams are accessible by highly chemoselective, diastereoselective, and enantioselective carbon-hydrogen insertion reactions of diazoacetamides. Competing aromatic cycloaddition or β-lactam formation via carbon-hydrogen insertion into a benzylic position can be minimized by the proper selection of chiral catalyst. Conformational influences are important in product preference.