443927-44-4

Basic information

• Product Name: 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)
• Synonyms: 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)
• CAS NO: 443927-44-4
• Molecular Weight: 1066.4
• Mol File: 443927-44-4.mol

Chemical Properties

• CAS DataBase Reference: 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)(443927-44-4)
• EPA Substance Registry System: 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)(443927-44-4)

Safety Data

• Hazardous Substances Data: 443927-44-4(Hazardous Substances Data)

Upstream product

• 322641-60-1 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine) 
• 7632-00-0 sodium nitrite 

Relevant articles and documents

Selective substitution of corroles: Nitration, hydroformylation, and chlorosulfonation

This work demonstrates the feasibility and powerfulness of electrophilic substitution on the peripheral carbon atoms of triarylcorroles as a synthetic tool to new derivatives. The large difference in the reactivity of the various carbon atoms on the macrocycle was shown to be of electronic rather than steric origin. A careful choice of reagents and a delicate control of reaction conditions allowed the selective syntheses of novel derivatives, in all of which substitution took place selectively in only the directly joined pyrrole rings of the macrocycle. This was proven by a combination of X-ray crystallography of the various products and detailed analysis of their NMR spectra.