444122-23-0Relevant articles and documents
Synthesis of a highly enantiomerically enriched silyllithium compound
Strohmann, Carsten,Hoernig, Jan,Auer, Dominik
, p. 766 - 767 (2002)
The highly enantiomerically enriched silyllithium compound lithiomethylphenyl(1-piperidinylmethyl)silane (4) reacts stereospecifically with chlorosilanes, but over a period of several hours slow racemization in solution at room temperature occurs, which c
A highly enantiomerically enriched lithiosilane by selective cleavage of a silicon-phenyl bond with lithium
Strohmann, Carsten,Daeschlein, Christian,Kellert, Marco,Auer, Dominik
, p. 4780 - 4782 (2007)
(Chemical Equation Presented) On the path to chiral polysilanes, the synthesis and first structural characterization of the enantiomerically pure tetrasilane (R)-3 was achieved. A new synthetic strategy was used, by which the cleavage of a silicon-phenyl