445040-77-7Relevant academic research and scientific papers
Practical and highly selective oxazolidinethione-based asymmetric acetate aldol reactions with aliphatic aldehydes.
Guz, Nathan R,Phillips, Andrew J
, p. 2253 - 2256 (2002)
[reaction: see text] The utility of a valine-derived oxazolidinethione for auxiliary-based asymmetric acetate aldol reactions is reported. Titanium(IV) chloride, along with (-)-sparteine and N-methylpyrrolidinone, is employed for enolization. Subsequent a
