445235-62-1

Upstream product

• 445235-60-9 methyl (2E,5R)-5,6-isopropylidenedioxy-2-methyl-2-hexenoate 
• 72496-37-8 ((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-acetaldehyde 
• 5754-34-7 2-((4R)-2,2-dimethyl-1,3-dioxolan-4-yl)ethanol 
• 98-88-4 benzoyl chloride 
• 445235-61-0 (2E,5R)-5,6-isopropylidenedioxy-2-methyl-2-hexen-1-ol 

Downstream Products

• 445235-63-2 (2R,3R,5R)-1-benzoyloxy-5,6-isopropylidenedioxy-2-methyl-2,3-hexanediol 
• 445235-64-3 (2R,4R,5R)-6-benzoyloxy-4,5-isopropylidenedioxy-5-methyl-1,2-hexanediol 
• 445235-68-7 (4S,5R)-5-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-propyl]-2,2,4-trimethyl-[1,3]dioxolane-4-carbaldehyde 
• 575456-24-5 Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester 
• 381665-45-8 (6R)-6-{(1E,3R,4R,6R,7Z,9Z,11E)-6-{[tert-butyl(dimethyl)silyl]oxy}-13-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxy-3-methyl-3-[(triethylsilyl)oxy]trideca-1,7,9,11-tetraen-1-yl}-5,6-dihydro-2H-pyran-2-one 
• 87810-56-8 (+)-fostriecin 
• 445235-72-3 (R)-6-((E)-2-{(4R,5R)-5-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-propyl]-2,2,4-trimethyl-[1,3]dioxolan-4-yl}-vinyl)-3-phenylselanyl-tetrahydro-pyran-2-one 
• 445235-69-8 ethyl (6E,8R,9R,11R)-11-tert-butyldimethylsiloxy-8,9-isopropylidenedioxy-12-p-methoxybenzyloxy-8-methyl-5-oxo-6-dodecenoate 

Relevant academic research and scientific papers

Total synthesis of an antitumor antibiotic, fostriecin (CI-920)

The total synthesis of an antitumor antibiotic, fostriecin (CI-920), via a highly convergent route is described. A characteristic feature of the present total synthesis is that the synthesis was achieved via a coupling procedure of three segments A, B, an

Total synthesis of fostriecin (CI-920) via a convergent route

Fostriecin, a potent and promising antitumor antibiotic, was stereoselectively synthesized via a convergent route involving a three-segement coupling procedure.